{4,40,6,60-Tetraiodo-2,20-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)] diphenolato} copper(II)

被引:3
作者
Kargar, Nadi [1 ]
Kia, Reza [2 ]
Shakarami, Tayebeh [1 ]
Tahir, Muhammad Nawaz [3 ]
机构
[1] Payame Noor Univ, Dept Chem, POB 9395-3697, Tehran, Iran
[2] Islamic Azad Univ, Dept Chem, Sci & Res Branch, Tehran, Iran
[3] Univ Sargodha, Dept Phys, Sargodha, Punjab, Pakistan
关键词
D O I
10.1107/S1600536812020387
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cu(C19H16I4N2O2)], the Cu II atom and the substituted C atom of the diamine segment lie on a crystallographic twofold rotation axis. The geometry around the Cu-II atom is distorted square- planar, which is supported by the N2O2 donor atoms of the coordinated Schiff base. The dihedral angle between the symmetry-related substituted benzene rings is 29.40 (19)degrees. In the crystal, a short I center dot center dot center dot I [3.8766 (6) angstrom] contact is present and links neighbouring molecules into chains propagating along the a axis.
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页数:7
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