{4,40,6,60-Tetraiodo-2,20-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)] diphenolato} copper(II)

被引:3
作者
Kargar, Nadi [1 ]
Kia, Reza [2 ]
Shakarami, Tayebeh [1 ]
Tahir, Muhammad Nawaz [3 ]
机构
[1] Payame Noor Univ, Dept Chem, POB 9395-3697, Tehran, Iran
[2] Islamic Azad Univ, Dept Chem, Sci & Res Branch, Tehran, Iran
[3] Univ Sargodha, Dept Phys, Sargodha, Punjab, Pakistan
关键词
D O I
10.1107/S1600536812020387
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cu(C19H16I4N2O2)], the Cu II atom and the substituted C atom of the diamine segment lie on a crystallographic twofold rotation axis. The geometry around the Cu-II atom is distorted square- planar, which is supported by the N2O2 donor atoms of the coordinated Schiff base. The dihedral angle between the symmetry-related substituted benzene rings is 29.40 (19)degrees. In the crystal, a short I center dot center dot center dot I [3.8766 (6) angstrom] contact is present and links neighbouring molecules into chains propagating along the a axis.
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页数:7
相关论文
共 8 条
[1]   TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].
ALLEN, FH ;
KENNARD, O ;
WATSON, DG ;
BRAMMER, L ;
ORPEN, AG ;
TAYLOR, R .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19
[2]  
Blower PJ, 1998, TRANSIT METAL CHEM, V23, P109
[3]   VAN DER WAALS VOLUMES + RADII [J].
BONDI, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+
[4]  
Bruker, 2005, APEX2 SAINT SADABS
[5]   LIGAND ENVIRONMENT AND THE STRUCTURE OF SCHIFF-BASE ADDUCTS AND TETRACOORDINATED METAL-CHELATES [J].
GARNOVSKII, AD ;
NIVOROZHKIN, AL ;
MINKIN, VI .
COORDINATION CHEMISTRY REVIEWS, 1993, 126 (1-2) :1-69
[6]   2-((E)-{3-[(E)-2-Hydroxy-3,5-diiodobenzylideneamino]-2,2-dimethylpropyl}iminomethyl)-4,6-diiodophenol [J].
Kargar, Hadi ;
Kia, Reza ;
Shakarami, Tayebeh ;
Tahir, Muhammad Nawaz .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 :O564-U1131
[7]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[8]   Structure validation in chemical crystallography [J].
Spek, Anthony L. .
ACTA CRYSTALLOGRAPHICA SECTION D-STRUCTURAL BIOLOGY, 2009, 65 :148-155