Crystal structure of poly[[mu(3)-4,4'-(4,4'bipyridine-2,6-diyl)dibenzoato]{mu(2)-4-[6(4-carboxyphenyl)-4,4'-bipyridin-4'- ium2-yl]benzoato}manganese(II)] hemihydrate]

被引：0
|
作者：
Li, Yaping [1 ]
Sung, Dajun [2 ]
Ming, Julia [3 ]
Han, Liying [4 ]
Su, Guanfang [1 ]
机构：
[1] Second Hosp Jilin Univ, Dept Ophthalmol, Changchun 130041, Jilin, Peoples R China
[2] Jilin Univ, China Japan Union Hosp, Dept Vasc Surg, 126 Xiantai St, Changchun 130033, Jilin, Peoples R China
[3] St Eriks Eye Hosp, Karolinska Inst, SE-11282 Stockholm, Sweden
[4] Second Hosp Jilin Univ, Dept Gynaecol, Changchun 130041, Jilin, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
crystal structure; Mn complex; metal-organic coordination polymer; hydrogen bonds;
D O I：
10.1107/S160053681402279X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, {[Mn(C24H14N2O4)(C24H16N2O4)]center dot- 0.5H(2)O} n, was obtained by the reaction of manganese nitrate with the ligand 4,4'-(4,4'-bipyridine-2,6-diyl) dibenzoic acid under hydrothermal conditions. The water O atom is located on a twofold rotation axis. The Mn2+ ion is heptacoordinated by six O atoms and one N atom from the ligands. In this structure, the ligands adopts two different forms, one completely deprotonated and one with a protonated N atom (pyridinium) and a carboxylic acid function. In the crystal, N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds consolidate the packing, forming a three-dimensional framework.
引用
收藏
页码：M374 / +
页数：14
相关论文
共 50 条
  • [21] Crystal structure of 4,4 '-(ethane-1,2-diyl)bis(2,6-di-bromoaniline)
    Hauptvogel, Ines
    Seichter, Wilhelm
    Weber, Edwin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 97 - +
  • [22] Crystal structure of a hydrogen-bonded 2:1 co-crystal of 4-nitrophenol and 4,4'-bipyridine
    Gotingco, Angela
    Contreras, Merary Villanueva
    Wolfarth, Jeanette A.
    Stieber, S. Chantal E.
    Marr, Zoe Y.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2024, 80 : 1135 - +
  • [23] Synthesis, structure and properties of [(ZnTPP)2(μ2-4,4′-bipyridine)] (H2TPP=5,10,15,20-tetraphenyl-21H, 23H-porphyrin; 4,4′-bipy=4,4′-bipyridine)
    Chen, Wen-Tong
    Yao, Zhong-Liang
    Wen, Ji-Wu
    Yi, Xiu-Guang
    Luo, Zhi-Gang
    JOURNAL OF CHEMICAL RESEARCH, 2013, (08) : 491 - 493
  • [24] A cadmium(II) coordination polymer:: Crystal structure and fluorescent property of [CdCl2(4,4′-bipyridine)]∞
    Lou, BY
    Wang, RH
    Xu, Y
    Yuan, DQ
    Zhou, YF
    Hong, MC
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (07) : 747 - 750
  • [25] A Cadmium（II） Coordination Polymer: Crystal Structure and Fluorescent Property of [CdCl2（4,4'-bipyridine）] ∞
    LOU Ben-Yong WANG Rui-Hu XU Ying YUAN Da-Qiang ZHOU You-Fu HONG Mao-Chun② (State Key Laboratory of Structural Chemistry
    结构化学, 2004, (07) : 747 - 750
  • [26] A Three-Interpenetrating Cobalt(II) Coordination Polymer Based on 4,4′-Azodibenzoic acid and 4,4′-Bipyridine: Solvothermal Synthesis, Crystal Structure and Thermal Stability Properties
    Han Yin-Feng
    Liu Tao
    Duan Wen-Zeng
    Wu Ren-Tao
    Li Ji-Kun
    Li Xiao-Yan
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2012, 28 (01) : 149 - 152
  • [27] A novel three-dimensional metal-organic interpenetrating framework constructed from mixed adipate and 4,4′-bipy ligands:: [Co(OOC(CH2)4COO)(4,4′-bipy)] (adipate = HOOC(CH2)4COOH, 4,4′-bipy=4,4′-bipyridine)
    Hao, N
    Shen, EH
    Li, YG
    Wang, EB
    Hu, CW
    Xu, L
    INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (04) : 510 - 512
  • [28] Hydrothermal Synthesis, Crystal Structure and Magnetic Property of a New Co(II) Complex: [Co(4,4′-bpy)2(H2O)2(4-FBA)2]•(4,4′-bpy)
    Zhang Bi-Song
    Zheng Miao
    Wu Chang-Sheng
    Li Yun-Xia
    Qiu Jian-Ping
    Zheng Yue-Qing
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 31 (04) : 577 - 581
  • [29] Synthesis, crystal structure and magnetic properties of two coordination polymers with 4-(4-carboxyphenyl)-4,2′:6′,4"-terpyridine ligand
    Wang, Meng-Si
    Li, Ming-Xing
    He, Xiang
    Shao, Min
    Wang, Zhao-Xi
    INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 42 : 38 - 41
  • [30] A Nearly Ideal One-Dimensional S=5/2 Antiferromagnet FeF3(4,4′-bpy) (4,4′-bpy=4,4′-bipyridyl) with Strong Intrachain Interactions
    Lu, Hongcheng
    Yamamoto, Takafumi
    Yoshimune, Wataru
    Hayashi, Naoaki
    Kobayashi, Yoji
    Ajiro, Yoshitami
    Kageyama, Hiroshi
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (31) : 9804 - 9807
12345