Crystal structure of poly[[mu(3)-4,4'-(4,4'bipyridine-2,6-diyl)dibenzoato]{mu(2)-4-[6(4-carboxyphenyl)-4,4'-bipyridin-4'- ium2-yl]benzoato}manganese(II)] hemihydrate]

被引：0

作者：

Li, Yaping ^{[1
]}

Sung, Dajun ^{[2
]}

Ming, Julia ^{[3
]}

Han, Liying ^{[4
]}

Su, Guanfang ^{[1
]}

机构：

[1] Second Hosp Jilin Univ, Dept Ophthalmol, Changchun 130041, Jilin, Peoples R China

[2] Jilin Univ, China Japan Union Hosp, Dept Vasc Surg, 126 Xiantai St, Changchun 130033, Jilin, Peoples R China

[3] St Eriks Eye Hosp, Karolinska Inst, SE-11282 Stockholm, Sweden

[4] Second Hosp Jilin Univ, Dept Gynaecol, Changchun 130041, Jilin, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

crystal structure; Mn complex; metal-organic coordination polymer; hydrogen bonds;

D O I：

10.1107/S160053681402279X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, {[Mn(C24H14N2O4)(C24H16N2O4)]center dot- 0.5H(2)O} n, was obtained by the reaction of manganese nitrate with the ligand 4,4'-(4,4'-bipyridine-2,6-diyl) dibenzoic acid under hydrothermal conditions. The water O atom is located on a twofold rotation axis. The Mn2+ ion is heptacoordinated by six O atoms and one N atom from the ligands. In this structure, the ligands adopts two different forms, one completely deprotonated and one with a protonated N atom (pyridinium) and a carboxylic acid function. In the crystal, N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds consolidate the packing, forming a three-dimensional framework.

引用

页码：M374 / +

页数：14

共 50 条

[1] Hydrothermal synthesis and crystal structure of a layered coordination polymer:: [Zn3(C2O4)3(4,4′-bipy)4]n (4,4′-bipy=4,4′-bipyridine)
Hao, N
Shen, EH
Li, YG
Wang, EB
Hu, CW
Xu, L
JOURNAL OF MOLECULAR STRUCTURE, 2004, 691 (1-3) : 273 - 277
[2] Crystal structure of 4,4 '-dimethoxy-2,2 '-bipyridine
Kusano, Yukiko
Ohno, Keiji
Fujihara, Takashi
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O623 - +
[3] Hydrothermal synthesis and crystal structure of a novel 4,4′-bipyridine bridging dumbbell-like dimeric pentamolybdate:: [4,4′-H2bipy]3[4,4′-Hbipy]2[(Mo5O17)2(4,4′-bipy)]
Niu, JY
Wang, ZL
Wang, JP
INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (04) : 556 - 558
[4] Crystal structure of 4,4'-(disulfanediyl)dibutanoic acid-4,4'-bipyridine (1/1)
Maria Atria, Ana
Teresa Garland, Maria
Baggio, Ricardo
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 157 - +
[5] A new one-dimensional 4,4′-bipy-bridged compound [Mn(hfac)2(4,4′-bipy)]n (hfac = hexafluoroacetetylacetonato;: 4,4′-bipy = 4,4′-bipyridine).: Synthesis, crystal structure and magnetic properties
Shen, HY
Liao, DZ
Jiang, ZH
Yan, SP
Sun, BW
Wang, GL
Yao, XK
Wang, HG
POLYHEDRON, 1998, 17 (11-12) : 1953 - 1957
[6] A 2D polymer constructed through bridging oxalato and 4,4′-bipyridine ligands:: crystal structure and magnetic behavior of [Cu3(μ-ox)3(μ-4,4′-bpy)2(4,4′-bpy)2]n
Castillo, O
Alonso, J
García-Couceiro, U
Luque, A
Román, P
INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (07) : 803 - 806
[7] Bis[4,4′-bipyridinium(1+)] 4,4′-bipyridinium(2+) dodecamolybdogermanate(4-) dihydrate
Sun, De-Wu
Zhai, Hong-Ju
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M2937 - M2939
[8] catena-Poly[[diaquabis(thiocyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ2N:N′] 4,4′-bipyridine solvate]
Yao, Rufu
Wang, Dong E.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M813 - U1176
[9] Synthesis, characterization and crystal structure of one Mn(II) complex with 4,4′-bisimidazolylbiphenyl and 4,4′-sulfonyldibenzoic acid
Zhang, Chun-Li
Qin, Ling
Zheng, He-Gen
INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 34 : 34 - 36
[10] Inclusion and intercalation of 4,4′-bipyridine in a zinc(II) aqua perchlorato complex [Zn(4,4′-bpy)(H2O)3(ClO4)](ClO4)•(4,4′-bpy)1.5•H2O
Liu, CM
You, XZ
Chen, W
JOURNAL OF COORDINATION CHEMISTRY, 1998, 46 (02) : 183 - 191

← 1 2 3 4 5 →