STRUCTURAL INVESTIGATIONS OF DIARYL DICHALCOGENIDES - THE MOLECULAR-STRUCTURES OF [2,4,6-(CF3)3C6H2S]2, [2,4,6-ME3C6H2TE]2 AND [2-ME2N-4,6-(CF3)2C6H2TE]2

被引：16

作者：

EDELMANN, A ^{[1
]}

BROOKER, S ^{[1
]}

BERTEL, N ^{[1
]}

NOLTEMEYER, M ^{[1
]}

ROESKY, HW ^{[1
]}

SHELDRICK, GM ^{[1
]}

EDELMANN, FT ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1992年 / 47卷 / 03期

关键词：

SULFUR; TELLURIUM; DISULFIDES; DITELLURIDES; X-RAY;

D O I：

10.1515/znb-1992-0302

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The molecular structures of [2,4,6-(CF3)3C6H2S]2 (1), [2,4,6-Me3C6H2Te]2 (2) and [2-Me2N-4,6-(CF3)2C6H2Te]2 (3) have been determined by X-ray diffraction. Crystal data: 1: orthorhombic, space group P2(1)2(1)2(1), Z = 4, a = 822.3(2), b = 1029.2(2), c = 2526.6(5) pm (2343 observed independent reflexions, R = 0.042); 2: orthorhombic, space group Iba2, Z = 8, a = 1546.5(2), b = 1578.4(2), c = 1483.9(1) pm (2051 observed independent reflexions, R = 0.030); 3: monoclinic, space group P2(1)/c, Z = 4, a = 1118.7(1), b = 1536.5(2), c = 1492.6(2) pm, beta = 98.97(1)-degrees (3033 observed independent reflexions, R = 0.025).

引用

页码：305 / 309

页数：5

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