SPECTROSCOPIC AND MAGNETIC STUDIES OF COMPLEXES OF D(10) CLOSED-SHELL IONS

被引：6

作者：

KIMACHI, S ^{[1
]}

IKEDA, S ^{[1
]}

MIKI, H ^{[1
]}

AZUMI, T ^{[1
]}

CROSBY, GA ^{[1
]}

机构：

[1] WASHINGTON STATE UNIV,DEPT CHEM,PULLMAN,WA 99164

来源：

COORDINATION CHEMISTRY REVIEWS | 1994年 / 132卷

关键词：

D O I：

10.1016/0010-8545(94)80022-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fluorescence, phosphorescence, and the triplet spin sublevel properties (zero-field splitting, total decay rate constants, and relative radiative decay rate constants for individual sublevels) are investigated for a series of complexes of the type MX2(phen), where M is Zn(II) or Cd(II), and X is Cl, Br, or I. The fluorescence and the phosphorescence are almost identical to those of free phen indicating that the emission is from the phen localized pipi* state. The rate constants for spin forbidden transitions increase as the atomic number of halogen increases. All the kinetic data as well as the zero-field splitting parameters are satisfactorily interpreted by a configurational mixing between the phen localized pipi* state and the halogen p to phen pi* ligand-ligand charge-transfer state.

引用

页码：43 / 50

页数：8