THE CRYSTAL-STRUCTURE OF (ASPH(4))(2)[OSN(OH)(CN)(4)]

被引：11
|
作者：
VANDERWESTHUIZEN, HJ [1 ]
BASSON, SS [1 ]
LEIPOLDT, JG [1 ]
PURCELL, W [1 ]
机构：
[1] UNIV ORANGE FREE STATE,DEPT CHEM,BLOEMFONTEIN 9300,SOUTH AFRICA
来源：
TRANSITION METAL CHEMISTRY | 1994年 / 19卷 / 06期
关键词：
D O I：
10.1007/BF00980407
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of (AsPh(4))(2)[OsN(OH)(CN)(4)] has been determined from three-dimensional X-ray diffraction data. The [OsN(OH)(CN)(4)](2-) ion has a distorted octahedral geometry with bond distances: Os drop N = 1.606(5), Os-OH = 2.123(5) and Os-C-av = 2.068(8) Angstrom. The osmium atom is displaced 0.26 Angstrom from the equatorial cyano-carbon atom plane.
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收藏
页码：582 / 584
页数：3
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