THE CRYSTAL-STRUCTURE OF (ASPH(4))(2)[OSN(OH)(CN)(4)]

被引：11

作者：

VANDERWESTHUIZEN, HJ ^{[1
]}

BASSON, SS ^{[1
]}

LEIPOLDT, JG ^{[1
]}

PURCELL, W ^{[1
]}

机构：

[1] UNIV ORANGE FREE STATE,DEPT CHEM,BLOEMFONTEIN 9300,SOUTH AFRICA

来源：

TRANSITION METAL CHEMISTRY | 1994年 / 19卷 / 06期

关键词：

D O I：

10.1007/BF00980407

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of (AsPh(4))(2)[OsN(OH)(CN)(4)] has been determined from three-dimensional X-ray diffraction data. The [OsN(OH)(CN)(4)](2-) ion has a distorted octahedral geometry with bond distances: Os drop N = 1.606(5), Os-OH = 2.123(5) and Os-C-av = 2.068(8) Angstrom. The osmium atom is displaced 0.26 Angstrom from the equatorial cyano-carbon atom plane.

引用

页码：582 / 584

页数：3

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