Crystal structure of poly[di-mu-aqua-[5-[(1Z)-2-(4-chlorophenyl)-1-cyano- ethenyl]-1,2,3,4-tetrazol-l-ido-kappa N}-sodium]

被引:1
|
作者
Mague, Joel T. [1 ]
Mohamed, Shaaban K. [2 ,3 ]
Akkurt, Mehmet [4 ]
EI-Saghier, Ahmed M. M. [5 ]
Albayati, Mustafa R. [6 ]
机构
[1] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA
[2] Manchester Metropolitan Univ, Chem & Environm Div, Manchester M1 5GD, Lancs, England
[3] Menia Univ, Fac Sci, Dept Chem, El Minia 61519, Egypt
[4] Erciyes Univ, Fac Sci, Dept Phys, TR-38039 Kayseri, Turkey
[5] Sohag Univ, Fac Sci, Dept Chem, Sohag 82524, Egypt
[6] Kirkuk Univ, Coll Sci, Dept Chem, Kirkuk, Iraq
基金
美国国家科学基金会;
关键词
crystal structure; sodium salt; tetrazoles; hydrogen bonding;
D O I
10.1107/S2056989015006325
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Na(C10H5ClN5)(H2O)(2)], infinite chains of [Na(H2O)(2)](+) cations having a diamond -shaped cross-section and running parallel to the b axis are formed. O-H center dot center dot center dot N hydrogen bonds to the anions generate layers parallel to (100) which have the chlorobenzenecyanoethenyl substituents protruding from both surfaces. The sodium ion makes a short contact of 2.4801 (13) angstrom with the N atom of the tetrazolide ring which is syn to the cyano N atom.
引用
收藏
页码:M102 / U90
页数:9
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