NEW HETEROAROMATIC COMPLEXING AGENTS AND LUMINESCENCE OF THEIR EUROPIUM(III) AND TERBIUM(III) CHELATES

被引：103
|
作者：
MUKKALA, VM
SUND, C
KWIATKOWSKI, M
PASANEN, P
HOGBERG, M
KANKARE, J
TAKALO, H
机构：
[1] UNIV TURKU,DEPT CHEM,SF-20500 TURKU 50,FINLAND
[2] CTR BIOTECHNOL,SF-20521 TURKU,FINLAND
来源：
HELVETICA CHIMICA ACTA | 1992年 / 75卷 / 05期
关键词：
D O I：
10.1002/hlca.19920750517
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Twelve heteroaromatic complexing agents 9a-l were synthesized with the purpose to develop suitable labels for time-resolved luminescence-based bioaffinity assays. The relative luminescence yields, excitation maxima, and emission decay constants of their europium(III) and terbium(III) chelates were determined. According to these results, 2,2',2'',2'''-[(2,2'-bipyridine-6,6'-diyl)bis(methylenenitrilo)]tetrakis(acetic acid) (9e) and 2,2',2'',2'''-[(2,2':6',2''-terpyridine-6,6''-diyl)bis(methylenenitrilo)]tetrakis(acetic acid) (9l) are the most promising agents.
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收藏
页码：1621 / 1632
页数：12
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