SYNTHESIS, X-RAY CRYSTAL-STRUCTURE AND MULTISTAGE REDOX PROPERTIES OF A SEVERELY-DISTORTED TETRATHIAFULVALENE DONOR

被引：49

作者：

BRYCE, MR

COFFIN, MA

HURSTHOUSE, MB

KARAULOV, AI

MULLEN, K

SCHEICH, H

机构：

[1] QUEEN MARY & WESTFIELD COLL,DEPT CHEM,LONDON E1 4NS,ENGLAND

[2] MAX PLANCK INST POLYMER RES,W-6500 MAINZ,GERMANY

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 42期

关键词：

D O I：

10.1016/S0040-4039(00)79456-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Compound (2b) has been synthesised in one step from 2,3-dipentylanthraquinone. The X-ray crystal structure of (2b) reveals that the central quinonoid ring is distorted into a boat form; the di-, tri- and tetra-cations derived from (2b) are observed by cyclic voltammetry.

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页码：6029 / 6032

页数：4

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