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SYNTHESIS, X-RAY CRYSTAL-STRUCTURE AND MULTISTAGE REDOX PROPERTIES OF A SEVERELY-DISTORTED TETRATHIAFULVALENE DONOR
被引:49
|作者:
BRYCE, MR
COFFIN, MA
HURSTHOUSE, MB
KARAULOV, AI
MULLEN, K
SCHEICH, H
机构:
[1] QUEEN MARY & WESTFIELD COLL,DEPT CHEM,LONDON E1 4NS,ENGLAND
[2] MAX PLANCK INST POLYMER RES,W-6500 MAINZ,GERMANY
关键词:
D O I:
10.1016/S0040-4039(00)79456-1
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
Compound (2b) has been synthesised in one step from 2,3-dipentylanthraquinone. The X-ray crystal structure of (2b) reveals that the central quinonoid ring is distorted into a boat form; the di-, tri- and tetra-cations derived from (2b) are observed by cyclic voltammetry.
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页码:6029 / 6032
页数:4
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