ACTIVE SPECIES ON COKED SILICA-ALUMINA CATALYST

被引:22
作者
MASSOTH, FE
MENON, PG
机构
[1] Gulf Research & Development Co., Pittsburgh, Pa. 15230
来源
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT | 1969年 / 8卷 / 03期
关键词
D O I
10.1021/i260031a014
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The rapid, initial temperature rise attending oxidation of coked silica-alumina catalysts is due to a highly reactive material residing on the coke surface. The active species is formed in the coking process and is present even after a mild prevolatilization treatment in nitrogen; but it may be removed or rendered inactive by pretreatment under vacuum or in nitrogen at high temperature. A hydrogen-rich coke layer on the exterior of the basic coke particle is believed to be responsible for the effect observed. © 1969, American Chemical Society. All rights reserved.
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页码:383 / &
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