MICELLE FORMATION IN MOLTEN ACETAMIDE

被引:17
|
作者
AKHTER, MS
ALAWI, SM
BOSE, AN
机构
[1] Department of Chemistry, University of Bahrain, Isa Town
关键词
ACETAMIDE; CMC; CONDUCTIVITY; MICELLES;
D O I
10.1016/0927-7757(94)02987-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The electrical conductivity of four surfactants, sodium caprylate, sodium laurate sodium palmitate and sodium stearate in molten acetamide has been determined at 90 degrees C. Conductivity measurements show that micelles are formed in acetamide solution. Critical micelle concentration (CMC) has been determined for each of the surfactants. It is suggested that the simplest formula of the ionic micelle is (S-)(n)(CH3CONH2)(x). At higher concentration the micelle may be of the forms (NaS)(m)(S-)(n)(CH3CONH2)(x) where NaS denotes sodium stearate.
引用
收藏
页码:173 / 176
页数:4
相关论文
共 50 条
  • [31] Micelle formation of Tween 20 nonionic surfactant in imidazolium ionic liquids
    Luczak, Justyna
    Latowska, Anna
    Hupka, Jan
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2015, 471 : 26 - 37
  • [32] Micelle and Bilayer Formation of Amphiphilic Janus Particles in a Slit-Pore
    Rosenthal, Gerald
    Klapp, Sabine H. L.
    INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2012, 13 (08) : 9431 - 9446
  • [33] Micelle formation of poly(vinyl phenol)-block-polystyrene by α,ω-diamines
    Yoshida, E
    Kunugi, S
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (17) : 3063 - 3067
  • [34] Effect of temperature on micelle formation in aqueous NaBr solutions of octyltrimethylammonium bromide
    Zielinski, R
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2001, 235 (02) : 201 - 209
  • [35] Cellulose Nanofibrils and Diblock Copolymer Complex: Micelle Formation and Enhanced Dispersibility
    Dong, Hong
    Napadensky, Eugene
    Orlicki, Joshua A.
    Snyder, James F.
    Chantawansri, Tanya L.
    Kapllani, Alda
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (02): : 1264 - 1271
  • [36] Spectroscopic and DFT studies to understand the liquid formation mechanism in the LiTFSI/acetamide complex system
    Hu, YS
    Wang, ZX
    Li, H
    Huang, XJ
    Chen, LQ
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2005, 61 (09) : 2009 - 2015
  • [37] Cobalt(II) chloride complex formation in acetamide-calcium nitrate tetrahydrate melts
    Savovic, J
    Nikolic, R
    Veselinovic, D
    JOURNAL OF SOLUTION CHEMISTRY, 2004, 33 (03) : 287 - 300
  • [38] Micellar behaviour of cetyltrimethylammonium bromide in N-methyl acetamide -: alkanol and N,N-dimethyl acetamide -: alkanol mixtures
    Akhter, MS
    Alawi, SM
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2002, 196 (2-3) : 163 - 174
  • [39] Thermodynamics of lead(II) halide complex formation in calcium nitrate tetrahydrate - Acetamide melts
    Gadzuric, SB
    Zsigrai, IJ
    Nikolic, RM
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 2001, 56 (12): : 832 - 836
  • [40] ACTIVITY OF ACETAMIDE IN ACETAMIDE-CALCIUM NITRATE MELT SOLUTIONS
    NIKOLIC, R
    RISTIC, G
    JOURNAL OF SOLUTION CHEMISTRY, 1994, 23 (07) : 787 - 794