MICELLE FORMATION IN MOLTEN ACETAMIDE

被引:17
|
作者
AKHTER, MS
ALAWI, SM
BOSE, AN
机构
[1] Department of Chemistry, University of Bahrain, Isa Town
关键词
ACETAMIDE; CMC; CONDUCTIVITY; MICELLES;
D O I
10.1016/0927-7757(94)02987-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The electrical conductivity of four surfactants, sodium caprylate, sodium laurate sodium palmitate and sodium stearate in molten acetamide has been determined at 90 degrees C. Conductivity measurements show that micelles are formed in acetamide solution. Critical micelle concentration (CMC) has been determined for each of the surfactants. It is suggested that the simplest formula of the ionic micelle is (S-)(n)(CH3CONH2)(x). At higher concentration the micelle may be of the forms (NaS)(m)(S-)(n)(CH3CONH2)(x) where NaS denotes sodium stearate.
引用
收藏
页码:173 / 176
页数:4
相关论文
共 50 条
  • [2] Conductance and surface tension of ionic surfactants in molten acetamide
    Akhter, MS
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1997, 125 (2-3) : 109 - 114
  • [3] Effect of acetamide on the critical micelle concentration of aqueous solutions of some surfactants
    Akhter, MS
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1997, 121 (2-3) : 103 - 109
  • [4] Cobalt(II) chloride complexes in molten acetamide
    Savovic, J
    Nikolic, R
    Kerridge, DH
    FLUID PHASE EQUILIBRIA, 1996, 118 (01) : 143 - 151
  • [5] Micelle formation of sodium hyodeoxycholate
    Matsuoka, Keisuke
    Takagi, Kaede
    Honda, Chikako
    CHEMISTRY AND PHYSICS OF LIPIDS, 2013, 172 : 6 - 13
  • [6] Studies on solvophobic interactions and micelle formation in non aqueous solvents
    Akhter, MS
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1999, 150 (1-3) : 25 - 30
  • [7] New room-temperature molten salt based on LiTFSI with acetamide and ethyleneurea
    Chen, RJ
    Wu, F
    Liang, HY
    Zhang, CZ
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2004, 25 (11): : 2108 - 2111
  • [8] Binary molten salt electrolytes based on LiClO4 with acetamide or ethyleneurea
    Chen, RJ
    Wu, F
    Liang, HY
    Mao, LC
    ACTA PHYSICO-CHIMICA SINICA, 2004, 20 (03) : 323 - 326
  • [9] Effect of N-Methyl Acetamide on the Critical Micelle Concentration of Aqueous Solutions of Some Surfactants
    Alawi, Sadeq M.
    Akhter, M. Salim
    JOURNAL OF THE KOREAN CHEMICAL SOCIETY-DAEHAN HWAHAK HOE JEE, 2011, 55 (02): : 163 - 168
  • [10] Micelle and Vesicle Formation of Amphiphilic Nanoparticles
    Nikolic, Marija S.
    Olsson, Charlotta
    Salcher, Andrea
    Kornowski, Andreas
    Rank, Anja
    Schubert, Rolf
    Froemsdorf, Andreas
    Weller, Horst
    Foerster, Stephan
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (15) : 2752 - 2754