PALLADIUM(0)-CATALYZED ALKYLATION OF THIOLS

被引：51

作者：

GOUX, C ^{[1
]}

LHOSTE, P ^{[1
]}

SINOU, D ^{[1
]}

机构：

[1] UNIV LYON 1,ESCIL,CNRS,SYNTH ASYMETR LAB,F-69622 VILLEURBANNE,FRANCE

来源：

TETRAHEDRON | 1994年 / 50卷 / 34期

关键词：

D O I：

10.1016/S0040-4020(01)81764-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium(0)-catalyzed alkylation of various allylic carbonates by aromatic thiols allowed the easy preparation of various allylic aryl sulphides in quite good yields. The reaction was regioselective with substitution at the less hindered side of the pi-allyl system whatever the temperature of the reaction, and was diastereoselective with net retention of configuration.

引用

页码：10321 / 10330

页数：10

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