ELECTROCHEMICAL PROCESSES OF CHLORINE-CHLORIDE SYSTEM ON PLATINUM-IRIDIUM-COATED TITANIUM ELECTRODES

被引：25

作者：

FAITA, G

FIORI, G

AUGUSTYN.JW

机构：

[1] Laboratory of Electrochemistry and Metallurgy, University of Milan, Milan

[2] Ecole Supérieure d'Electrochimie et Electrometallurgie, Grenoble

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1969年 / 116卷 / 07期

关键词：

D O I：

10.1149/1.2412172

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Anodic and cathodic processes of the Cl2/Cl− system on Ti/Pt-Ir (30% Ir) in comparison with Ti/Pt electrodes were examined. The anodic Cl2 evolution follows the same scheme on both the electrodes [FORMULLA OMITTED] but Ti/Pt electrodes undergo a marked passivation for ηan > 0.2V, whereas the passivation on Ti/Pt-Ir electrodes is important only at overvoltages higher than 0.5V. Such a difference in passivation is noted also in the cathodic process: on Ti/Pt-Ir electrodes in fact, at low overvoltages, the process follows the scheme [FORMULLA OMITTED] due to the higher catalytic activity of the surface. © 1969, The Electrochemical Society, Inc. All rights reserved.

引用

页码：928 / &