Synthesis, crystal structure, photoluminescent and antimicrobial properties of a thiocyanato-bridged copper(II) coordination polymer

被引:8
作者
Chimaine, Feudjio Tsague [1 ]
Yufanyi, Divine Mbom [2 ]
Yuoh, Amah Colette Benedicta [1 ]
Eni, Donatus Bekindaka [1 ]
Agwara, Moise Ondoh [1 ]
机构
[1] Univ Yaounde I, Dept Inorgan Chem, POB 812 Yaounde, Yaounde, Cameroon
[2] Univ Bamenda, Dept Chem, POB 39 Bambili, Bamenda, Cameroon
来源
COGENT CHEMISTRY | 2016年 / 2卷
关键词
crystal structure; copper(II); photoluminescence; antimicrobial properties; thiocyanate;
D O I
10.1080/23312009.2016.1253905
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A Cu(II) 1D polymer with mixed ligands (SCN- and pyridine) has been synthesized and characterized by elemental analyses, IR, UV-visible and TG-DTA analytical techniques. The crystal structure was determined by single-crystal X-ray diffraction analyses. The complex crystallizes in the triclinic crystal system with space group P (1) over bar with one formula unit. Each Cu(II) atom is six coordinate with two N atoms of two pyridine molecules, two N atoms and two S-atoms from bridging SCN anions giving a distorted octahedral geometry with a CuS2N4 chromophore. The spectroscopic, photoluminescent and the antimicrobial activities of the synthesized complex were investigated.
引用
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页数:13
相关论文
共 47 条
  • [31] Prins LJ, 2001, ANGEW CHEM INT EDIT, V40, P2382, DOI 10.1002/1521-3773(20010702)40:13<2382::AID-ANIE2382>3.0.CO
  • [32] 2-G
  • [33] Copper(II) complexes of N(4)-substituted thiosemicarbazones derived from pyridine-2-carbaldehyde:: Crystal structure of a binuclear complex
    Rapheal, P. F.
    Manoj, E.
    Kurup, M. R. Prathapachandra
    [J]. POLYHEDRON, 2007, 26 (04) : 818 - 828
  • [34] Synthesis, crystal structures and properties of ternary copper(II) complexes having 2,2′-bipyridine and α-amino acid salicylaldiminates as models for the type-2 sites in copper oxidases
    Reddy, PAN
    Nethaji, M
    Chakravarty, AR
    [J]. INORGANICA CHIMICA ACTA, 2002, 337 : 450 - 458
  • [35] Metal-organic frameworks: a new class of porous materials
    Rowsell, JLC
    Yaghi, OM
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 73 (1-2) : 3 - 14
  • [36] Sheldrick G. M., 1997, SHELXS 97 SHELXL 97
  • [37] Synthesis and crystal structure of a novel polymeric thiocyanato-bridged heteronuclear complex of copper(II) and cadmium(II)
    Shen, L
    Feng, XW
    [J]. STRUCTURAL CHEMISTRY, 2002, 13 (5-6) : 437 - 441
  • [38] A 2D thiocyanato-bridged copper(II)-manganese(II) bimetallic coordination polymer with ferromagnetic interactions
    Shi, JM
    Xu, W
    Zhao, B
    Cheng, P
    Liao, DZ
    Chen, XY
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (01) : 55 - 58
  • [39] Tabong C. D., 2016, ADV CHEM, P8, DOI 10.1155/2016/5049718
  • [40] catena-Poly[[(pyridine-κN)copper(II)]-μ3-pyridine-2,6-dicarboxylato-κ3O2:O2′,N,O6:O6′]
    Trivedi, Manoj
    Pandey, Daya Shankar
    Rath, Nigam P.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M303 - U705