Synthesis, crystal structure, photoluminescent and antimicrobial properties of a thiocyanato-bridged copper(II) coordination polymer

被引：8

作者：

Chimaine, Feudjio Tsague ^{[1
]}

Yufanyi, Divine Mbom ^{[2
]}

Yuoh, Amah Colette Benedicta ^{[1
]}

Eni, Donatus Bekindaka ^{[1
]}

Agwara, Moise Ondoh ^{[1
]}

机构：

[1] Univ Yaounde I, Dept Inorgan Chem, POB 812 Yaounde, Yaounde, Cameroon

[2] Univ Bamenda, Dept Chem, POB 39 Bambili, Bamenda, Cameroon

来源：

COGENT CHEMISTRY | 2016年 / 2卷

关键词：

crystal structure; copper(II); photoluminescence; antimicrobial properties; thiocyanate;

D O I：

10.1080/23312009.2016.1253905

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Cu(II) 1D polymer with mixed ligands (SCN- and pyridine) has been synthesized and characterized by elemental analyses, IR, UV-visible and TG-DTA analytical techniques. The crystal structure was determined by single-crystal X-ray diffraction analyses. The complex crystallizes in the triclinic crystal system with space group P (1) over bar with one formula unit. Each Cu(II) atom is six coordinate with two N atoms of two pyridine molecules, two N atoms and two S-atoms from bridging SCN anions giving a distorted octahedral geometry with a CuS2N4 chromophore. The spectroscopic, photoluminescent and the antimicrobial activities of the synthesized complex were investigated.

引用

页数：13

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