DETERMINATION OF CHEMICAL-COMPOSITION DISTRIBUTION OF POLY(METHYL METHACRYLATE)-GRAFT-POLYSTYRENE PREPARED FROM OMEGA-P-VINYLBENZYL POLYSTYRENE MACROMONOMER BY ADSORPTION HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY

被引：21

作者：

TANAKA, S

UNO, M

TERAMACHI, S

TSUKAHARA, Y

机构：

[1] KOGAKUIN UNIV,DEPT APPL CHEM,HACHIOJI,TOKYO 192,JAPAN

[2] KYOTO INST TECHNOL,DEPT MAT SCI,MATSUGASAKI,KYOTO 606,JAPAN

来源：

POLYMER | 1995年 / 36卷 / 11期

关键词：

CCD DETERMINATION; PMMA-G-PS; HPLC;

D O I：

10.1016/0032-3861(95)95300-P

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Chemical composition distributions (CCDs) of poly(methyl methacrylate)-graft-polystyrene samples with different compositions and conversions synthesized from methyl methacrylate and omega-p-vinylbenzyl polystyrene macromonomer were determined by high-performance liquid chromatography using both reversed-phase and normal-phase adsorption modes. The good agreement between CCDs obtained by both modes showed that the molecular-weight effect on the CCDs is negligible. All samples have broad CCDs. As the macromonomer content increases, the CCD becomes sharper. These results are in accordance with the theoretical predictions. As the conversion increases at the same feed composition, the CCD becomes broader towards the low-macromonomer-content side, which is in contrast to the CCDs of the samples obtained previously from omega-methacryloyl polystyrene macromonomer.

引用

页码：2219 / 2225

页数：7

共 14 条

[1] BERGER KC, 1989, POLYM HDB, P67
[2] GLOCKNER G, 1986, ADV POLYM SCI, V79, P159
[3] ANALYSIS OF LINEAR METHODS FOR DETERMINING COPOLYMERIZATION REACTIVITY RATIOS .1. NEW IMPROVED LINEAR GRAPHIC METHOD
KELEN, T
TUDOS, F
[J]. JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1975, A 9 (01): : 1 - 27
[4] MITA I, 1987, J MACROMOL SCI R M C, VC27, P91
[5] ANALYSIS OF CHEMICAL-COMPOSITION DISTRIBUTION OF STYRENE METHYL-METHACRYLATE COPOLYMER BY HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY
SATO, H
TAKEUCHI, H
TANAKA, Y
[J]. MACROMOLECULES, 1986, 19 (10) : 2613 - 2617
[6] GRAFT COPOLYMER STATISTICS .2. APPLICATION TO GRAFT-COPOLYMERS PREPARED FROM MACROMONOMERS
STEJSKAL, J
KRATOCHVIL, P
JENKINS, AD
[J]. MACROMOLECULES, 1987, 20 (01) : 181 - 185
[7] DISTRIBUTION OF CHEMICAL-COMPOSITION OF STATISTICAL COPOLYMERS FROM THE CONVERSION DEPENDENCES OF COPOLYMER OR RESIDUAL MONOMER MIXTURE COMPOSITION
STEJSKAL, J
KRATOCHVIL, P
STRAKOVA, D
PROCHAZKA, O
[J]. MACROMOLECULES, 1986, 19 (06) : 1575 - 1580
[8] STATISTICAL CHEMICAL HETEROGENEITY OF COPOLYMERS - MODIFICATION OF THE STOCKMAYER DISTRIBUTION FUNCTION OF CHEMICAL-COMPOSITION
STEJSKAL, J
KRATOCHVIL, P
[J]. MACROMOLECULES, 1987, 20 (10) : 2624 - 2628
[9] CHEMICAL-COMPOSITION DISTRIBUTION OF A GRAFT COPOLYMER PREPARED FROM MACROMONOMER - FRACTIONATION IN DEMIXING SOLVENTS
STEJSKAL, J
STRAKOVA, D
KRATOCHVIL, P
SMITH, SD
MCGRATH, JE
[J]. MACROMOLECULES, 1989, 22 (02) : 861 - 865
[10] COMPOSITIONAL FRACTIONATION OF COPOLY(STYRENE METHYL-METHACRYLATE) BY NORMAL-PHASE AND REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY
TERAMACHI, S
HASEGAWA, A
MOTOYAMA, K
[J]. POLYMER JOURNAL, 1990, 22 (06) : 489 - 496

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