SURFACE ORGANOMETALLIC CHEMISTRY OF TIN - REACTION OF (N-C4H9)3SNH WITH THE SURFACE OF A SILICA-ALUMINA - A C-13 AND SN-119 SOLID-STATE NMR INVESTIGATION

被引：21

作者：

NEDEZ, C

CHOPLIN, A

LEFEBVRE, F

BASSET, JM

机构：

[1] ESCIL,CNRS,CPE 48,UMR,CHIM ORGANOMET SURFACE LAB,43 BD 11 NOVEMBRE 1918,F-69616 VILLEURBANNE,FRANCE

[2] INST RECH CATALYSE,F-69626 VILLEURBANNE,FRANCE

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 07期

关键词：

D O I：

10.1021/ic00085a061

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The well-defined organometallic fragment -X-O-Sn(n-C4H9)3 has been characterized on silica-alumina. Surprisingly, only the species with X = Si is observed, while it is known that alumina can also form such complexes where tin can be in tetrahedral or octahedral form. This shows that a nonuniform oxide surface can lead to a uniform surface organometallic complex, the reaction of the starting organometallic complex with the surface being highly selective.

引用

页码：1575 / 1578

页数：4

共 25 条

[21] REACTIONS OF N-BUTYLIN HYDRIDES WITH N-BUTYLTIN HALIDES [J].