ANALYTICAL IMPLICATIONS OF DIFFERENTIAL PULSE POLAROGRAPHY OF IRREVERSIBLE REACTIONS FROM DIGITAL-SIMULATION

被引：36

作者：

DILLARD, JW ^{[1
]}

ODEA, JJ ^{[1
]}

OSTERYOUNG, RA ^{[1
]}

机构：

[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523

来源：

ANALYTICAL CHEMISTRY | 1979年 / 51卷 / 01期

关键词：

D O I：

10.1021/ac50037a035

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Explicit finite difference simulations of differential pulse polarography have been developed for evaluating the analytical applications of differential pulse polarography to irreversible and quasireversible electron transfer reactions. From simulation data, detailed prediction of polarographic peak shape and position as a function of pulse height, pulse time, and drop time is possible. Optimum conditions for analytical application of differential pulse polarography are discussed. © 1979, American Chemical Society. All rights reserved.

引用

页码：115 / 119

页数：5

共 13 条

[1]

BIRKE RL, 1978, ANAL CHEM, V50, P1489, DOI 10.1021/ac50033a027

[2]

CHRISTIE JH, 1966, ELECTROCHIM ACTA, V11, P1525

[3]

DELAHAY P, 1954, NEW INSTRUMENTAL MET, pCH4

[4] DIGITAL-SIMULATION OF DIFFERENTIAL PULSE POLAROGRAPHY [J].

DILLARD, JW ;

HANCK, KW .

ANALYTICAL CHEMISTRY, 1976, 48 (01) :218-222

[5] DIGITAL-SIMULATION OF DIFFERENTIAL PULSE POLAROGRAPHY WITH INCREMENTAL TIME CHANGE [J].

DILLARD, JW ;

TURNER, JA ;

OSTERYOUNG, RA .

ANALYTICAL CHEMISTRY, 1977, 49 (08) :1246-1250

[6]

Feldberg S. W., 1969, ELECTROANALYTICAL CH, V3, P199

[7]

KORYTA J, 1962, ELECTROCHIM ACTA, V6, P67

[8]

KOUTECKY J, 1953, CHEM LISTY, V47, P323

[9]

Meites L, 1965, POLAROGRAPHIC TECHNI, P240

[10] EVALUATION OF ANALYTICAL PULSE POLAROGRAPHY [J].

PARRY, EP ;

OSTERYOUNG, RA .

ANALYTICAL CHEMISTRY, 1965, 37 (13) :1634-+

← 1 2 →