[R(3)SI-ARENE](+) SIGMA-COMPLEXES IN THE GAS-PHASE

被引：20

作者：

CACACE, F

ATTINA, M

FORNARINI, S

机构：

[1] Università di Roma, Rome, 1-00185

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 06期

关键词：

ARENE COMPLEXES; GAS-PHASE CHEMISTRY; MASS SPECTROMETRY; SILYL CATIONS;

D O I：

10.1002/anie.199506541

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

σ Complex 1 or π complex 2? This is a controversial question for [R3Si–arene]+ adducts. A crucial test based on their reactivity, toward selected nucleophiles provides convincing evidence for the existence of the σ complex 1 in the gas phase. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：654 / 655

页数：2

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