INTERCONVERSION OF AU-I/II/III CENTERS IN THIOETHER MACROCYCLIC COMPLEXES - THE SYNTHESIS, STRUCTURES AND REDOX PROPERTIES OF [AU([18]ANES6)]PF6 AND [AU2([15]ANES5)(2)][B(C6F5)(4)](2)

被引：29

作者：

BLAKE, AJ ^{[1
]}

TAYLOR, A ^{[1
]}

SCHRODER, M ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,W MAINS RD,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 13期

关键词：

D O I：

10.1039/c39930001097

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The interconversion of mononuclear Au(I)/II/III centres in thioether macrocyclic complexes is related to the stereochemical properties of the parent Au(I) species; the structure of [Au([18]aneS6)]+ shows a distorted tetrahedral [2 + 2] coordination at Au(I), while the Au(I) complex of [15]aneS5 is binuclear with Au(I) ions bridging [15]aneS5 ligands in a macrobicyclic structure.

引用

页码：1097 / 1098

页数：2

共 20 条

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