INTERCONVERSION OF AU-I/II/III CENTERS IN THIOETHER MACROCYCLIC COMPLEXES - THE SYNTHESIS, STRUCTURES AND REDOX PROPERTIES OF [AU([18]ANES6)]PF6 AND [AU2([15]ANES5)(2)][B(C6F5)(4)](2)

被引:29
|
作者
BLAKE, AJ [1 ]
TAYLOR, A [1 ]
SCHRODER, M [1 ]
机构
[1] UNIV EDINBURGH,DEPT CHEM,W MAINS RD,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND
关键词
D O I
10.1039/c39930001097
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The interconversion of mononuclear Au(I)/II/III centres in thioether macrocyclic complexes is related to the stereochemical properties of the parent Au(I) species; the structure of [Au([18]aneS6)]+ shows a distorted tetrahedral [2 + 2] coordination at Au(I), while the Au(I) complex of [15]aneS5 is binuclear with Au(I) ions bridging [15]aneS5 ligands in a macrobicyclic structure.
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页码:1097 / 1098
页数:2
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