Crystal structure of (E)-1-{[(3,5-dimethylphenyl)imino]methyl}naphthalen-2-ol

被引:14
作者
Abu-Dief, Ahmed M. [1 ]
Abdelbaky, Mohammed S. M. [2 ]
Garcia-Granda, Santiago [2 ]
机构
[1] Sohag Univ, Dept Chem, Fac Sci, Sohag 82524, Egypt
[2] Oviedo Univ CINN, Dept Phys & Analyt Chem, Fac Chem, Oviedo 33006, Spain
关键词
crystal structure; Schiff base; naphthalen-2-ol; imino; hydrogen bonding;
D O I
10.1107/S2056989015011548
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C19H17NO, has an E conformation about the N=C bond. The molecule is relatively planar, with the benzene ring and naphthalene ring plane being inclined to one another by 4.28 (10)degrees. Thereis an intramolecular O-H center dot center dot center dot N hydrogen bond generating an S(6) ring motif. In the crystal, molecules are linked via C-H center dot center dot center dot O hydrogen bonds, forming chains propagating along [100]. Within the chains there are pi-pi interactions involving the benzene ring and the naphthalene ring system of an adjacent molecule [inter-centroid distance = 3.6405 (14) angstrom].
引用
收藏
页码:O496 / U385
页数:9
相关论文
共 13 条
[11]  
Schiff H., 1864, CHEM PHARM S, V3, P343
[12]  
Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930]
[13]   Structure validation in chemical crystallography [J].
Spek, Anthony L. .
ACTA CRYSTALLOGRAPHICA SECTION D-STRUCTURAL BIOLOGY, 2009, 65 :148-155