DETERMINATION OF THE SURFACE-ACIDITY OF LAYERED METAL PHOSPHATES BY NH3 TEMPERATURE-PROGRAMMED DESORPTION

被引:9
作者
BAGNASCO, G
CIAMBELLI, P
LAGINESTRA, A
TURCO, M
机构
[1] UNIV NAPOLI FEDERICO II,DIPARTIMENTO CHIM,I-80134 NAPLES,ITALY
[2] UNIV ROME LA SAPIENZA,DEPARTIMENTO CHIM,I-00185 ROME,ITALY
关键词
D O I
10.1016/0040-6031(90)80330-2
中图分类号
O414.1 [热力学];
学科分类号
摘要
The acid properties of layered Me phosphates (MeTi, Ge, Zr, Sn) were determined by NH3 temperature-programmed desorption. Careful establishment of the preheating conditions suppressed interference from NH3 intercalation and allowed the surface acidity to be measured. A scale of acidity strength in line with the catalytic behaviour of these phosphates in acid-catalysed reactions was obtained. © 1990.
引用
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页码:91 / 97
页数:7
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