BENZENE POLYMERIZATION IN 1-ETHYL-3-METHYLIMIDAZOLIUM CHLORIDE ALCL3 IONIC LIQUID

被引：46
作者：
GOLDENBERG, LM
OSTERYOUNG, RA
机构：
[1] N CAROLINA STATE UNIV,DEPT CHEM,RALEIGH,NC 27695
[2] CHERNOGOLOVKA CHEM PHYS INST,CHERNOGOLOVKA 142432,RUSSIA
来源：
SYNTHETIC METALS | 1994年 / 64卷 / 01期
关键词：
D O I：
10.1016/0379-6779(94)90276-3
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Poly(p-phenylene) films were prepared by the electropolymerization of benzene in an ambient-temperature molten salt, or ionic liquid, consisting of 1-ethyl-3-methylimidazolium chloride-aluminum chloride. Polymerization was carried out in melts of varying acidity in neutral buffered melts. The films were then examined in 1-ethyl-3-methylimidazolium chloride-aluminum chloride melts of varying acidity. The polymerization and electrochemical behavior of the films are independent of melt acidity; the films show reasonably facile electrochemical behavior.
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页码：63 / 68
页数：6
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