HEXANUCLEAR FERRIC COMPLEX WITH A NOVEL S = 5 GROUND-STATE

被引：22

作者：

HARVEY, DF

CHRISTMAS, CA

MCCUSKER, JK

HAGEN, PM

CHADHA, RK

HENDRICKSON, DN

机构：

[1] Department of Chemistry-0506, University of California at San Diego, La Jolla, California

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 05期

关键词：

D O I：

10.1002/anie.199105981

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The iron complex 1 shows novel, magnetic properties. Its spin ground state is S = 5, even though all six iron centers are high-spin Fe(III) ions. Magnetic measurements revealed an increase in mu-eff with decreasing temperature. Complex 1 was also characterized by X-ray structure analysis.

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页码：598 / 600

页数：3

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