THE ELIMINATION OF MATRIX EFFECTS IN THE DETERMINATION OF FLUORINE BY PROTON-INDUCED PROMPT GAMMA-SPECTROMETRY

被引:6
作者
OLIVIER, C
MORLAND, HJ
机构
[1] Department of Chemistry, University of Stellenbosch, Stellenbosch
来源
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES | 1991年 / 151卷 / 01期
关键词
D O I
10.1007/BF02040131
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
By measuring the yield of prompt gamma-rays, induced by energetic protons, the ratio of the ranges in sample and standard was used in the average cross-section method to determine fluorine. By spiking the sample with known amounts of a lithium compound, a non-analyte element (absent from the sample), the appropriate ranges in the samples were determined by measuring the prompt gamma-rays induced in the non-analyte spike. Fluorine was determined in ores and ivory and the method was tested by analyzing the standard reference materials SRM 91, SRM 120c and SRM 694.
引用
收藏
页码:63 / 73
页数:11
相关论文
共 12 条
[1]   On the alpha particles of radium, and their loss of range in passing through various atoms and molecules [J].
Bragg, W. H. ;
Elder, M. A. .
PHILOSOPHICAL MAGAZINE, 1905, 10 (55-60) :318-340
[2]  
GIHWALA D, 1982, THESIS U CAPE TOWN
[3]   THE SEARCH FOR MOLECULAR EFFECTS IN RANGE CORRECTIONS - PHOSPHORUS DETERMINATION BY PROTON-BOMBARDMENT [J].
MORLAND, HJ ;
OLIVIER, C ;
DEWET, BS ;
PEISACH, M .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1988, 35 (3-4) :253-256
[4]   CORRECTION OF PROTON RANGES IN UNKNOWN SAMPLES BY SPIKING [J].
OLIVIER, C ;
MORLAND, HJ ;
PEISACH, M .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1988, 35 (3-4) :263-267
[5]   DETERMINATION OF LITHIUM BY BORON SPIKING AND PROTON IRRADIATION [J].
OLIVIER, C ;
MORLAND, HJ ;
DEWET, BS .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES, 1988, 123 (02) :443-460
[6]  
OLIVIER C, 1987, RADIOCHIM ACTA, V42, P9
[7]  
OLIVIER C, 1990, S AFR J CHEM-S-AFR T, V43, P131
[8]   RANGE CORRECTIONS USING NONANALYTE SPIKING [J].
OLIVIER, C ;
MORLAND, HJ .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-LETTERS, 1990, 146 (06) :367-374
[9]  
OLIVIER C, 1986, J RADIOANAL NUCL CHE, V98, P443
[10]   SENSITIVITIES FOR ACTIVATION ANALYSIS OF 15 LIGHT ELEMENTS WITH 18-MEV HELIUM-3 PARTICLES [J].
RICCI, E ;
HAHN, RL .
ANALYTICAL CHEMISTRY, 1967, 39 (07) :794-&