FLOW REACTOR STUDIES OF CARBON-MONOXIDE HYDROGEN OXYGEN KINETICS

被引：82

作者：

YETTER, RA ^{[1
]}

DRYER, FL ^{[1
]}

RABITZ, H ^{[1
]}

机构：

[1] PRINCETON UNIV,DEPT CHEM,PRINCETON,NJ 08544

来源：

COMBUSTION SCIENCE AND TECHNOLOGY | 1991年 / 79卷 / 1-3期

关键词：

KINETICS; CO/H-2; OXIDATION; FLOW REACTOR;

D O I：

10.1080/00102209108951760

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

New data on the kinetics of CO/H2O/O2and H2/O2mixtures in the temperature range of 852–1138 K and at 1 atmosphere pressure are reported. The data were obtained from adiabatic, constant pressure flow reactor experiments for variations in the initial carbon, hydrogen, and oxygen contents of the mixture and also for variations in the initial temperature. In particular, the results define explosion limit temperatures for near stoichiometric mixtures of CO/H2O/O2and H2/O2systems at atmospheric pressure without the presence of surfaces and also demonstrate the complex relationship between water vapor concentration and the carbon monoxide oxidation rate. © 1991, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：129 / 140

页数：12

共 13 条

[1]

CHANG EJ, 1989, THESIS PRINCETON U P

[2]

DRYER FL, 1973, 14 S INT COMB COMB I, P987

[3]

DRYER FL, 1972, AMS T1034 PRINC U DE

[4]

EUCHNER JA, 1980, MAE1497T PRINC U DEP

[5] ISOTHERMAL QUENCHING OF THE OXIDATION OF WET CO [J].

HARDY, JE ;

LYON, RK .

COMBUSTION AND FLAME, 1980, 39 (03) :317-320

[6]

HAUTMAN DJ, 1980, MAE1471T PRINC U DEP

[7]

NORTON T, 1989, COMMUNICATION

[8]

PROSCIA WM, 1983, MAE1625T PRINC U DEP

[9]

STEIN Y, 1986, FAL TECHN M E SECT C

[10] SOME INTERPRETIVE ASPECTS OF ELEMENTARY SENSITIVITY GRADIENTS IN COMBUSTION KINETICS MODELING [J].

YETTER, RA ;

DRYER, FL ;

RABITZ, H .

COMBUSTION AND FLAME, 1985, 59 (02) :107-133

← 1 2 →