HUNTITE-BORATE CRYSTALLIZATION IN STOICHIOMETRIC MELTS

被引:3
作者
CHANI, VI [1 ]
SHIMAMURA, K [1 ]
INOUE, K [1 ]
FUKUDA, T [1 ]
机构
[1] TOHOKU UNIV,INST MAT RES,SENDAI,MIYAGI 980,JAPAN
关键词
D O I
10.1016/0022-0248(93)90119-H
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The crystal formation of huntite borates LnAl3(BO3)4, where Ln is Yb or a combination of (Yb,Tm,Er) doped by Bi3+, Li+, Ti4+, V5+, Mo6+ and Ge4+, was observed in stoichiometric systems after heating to 1340-1370-degrees-C and cooling to room temperature. All crystals grown by spontaneous crystallization were studied by X-ray diffraction powder analysis and only the huntite-borate phase was detected. The dependence of stability of the huntite-borate structure on crystal composition is discussed.
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页码:181 / 184
页数:4
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