CAPTO-DATIVE SUBSTITUENT EFFECTS .3. SYNTHESIS AND INTRA-MOLECULAR 1,3 CL,H DISPROPORTIONATION OF ETHYL 2,2-DICHLORO-2-(DIMETHYLAMINO)-ACETATE

被引：10

作者：

HUYS, F ^{[1
]}

MERENYI, R ^{[1
]}

JANOUSEK, Z ^{[1
]}

STELLA, L ^{[1
]}

VIEHE, HG ^{[1
]}

机构：

[1] CATHOLIC UNIV LOUVAIN,CHIM ORGAN LAB,B-1348 LOUVAIN LA NEUVE,BELGIUM

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 08期

关键词：

D O I：

10.1002/anie.197906151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Compounds having geminal capto‐dative substitutents contain a donor and an acceptor group bonded to the same C atom;such substitution stabilizes radicals. Compound 1 is an example; its remarkable Cl,H disproportionation to give the glyoxalic ester derivative 2 probably proceeds via a radical. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：615 / 616

页数：2

共 12 条

[1] Some derivatives of as-dipropyl- and -diamyl-oxamic acids.
Atkinson, HM
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1914, 105 : 1290 - 1296
[2] BARTHOLOMEW D, TETRAHEDRON LETT
[3] Bohme H., 1979, ADV ORGANIC CHEM, V9
[4] BOHME H, 1976, ADV ORGANIC CHEM, V9
[5] HUYS F, 1979, THESIS U LOUVAIN LA
[6] CAPTO-DATIVE SUBSTITUTION EFFECTS .4. INTRA-MOLECULAR CL,H DISPROPORTIONATION OF AN OXAMIDE CHLORIDE - ENTRY TO IMIDAZOLE DERIVATIVES
JANOUSEK, Z
HUYS, F
RENE, L
MASQUELIER, M
STELLA, L
MERENYI, R
VIEHE, HG
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (08): : 616 - 617
[7] JANOUSEK Z, 1979, ANGEW CHEM, V91, P651
[8] POMMELET JC, UNPUBLISHED
[9] STABILIZATION OF RADICALS BY CAPTO-DATIVE SUBSTITUTION-C-C ADDITION TO RADICOPHILIC OLEFINS
STELLA, L
JANOUSEK, Z
MERENYI, R
VIEHE, HG
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (09): : 691 - 692
[10] STELLA L, 1978, ANGEW CHEM, V90, P741

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