CAPTO-DATIVE SUBSTITUENT EFFECTS .3. SYNTHESIS AND INTRA-MOLECULAR 1,3 CL,H DISPROPORTIONATION OF ETHYL 2,2-DICHLORO-2-(DIMETHYLAMINO)-ACETATE

被引：10

作者：

HUYS, F ^{[1
]}

MERENYI, R ^{[1
]}

JANOUSEK, Z ^{[1
]}

STELLA, L ^{[1
]}

VIEHE, HG ^{[1
]}

机构：

[1] CATHOLIC UNIV LOUVAIN,CHIM ORGAN LAB,B-1348 LOUVAIN LA NEUVE,BELGIUM

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 08期

关键词：

D O I：

10.1002/anie.197906151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Compounds having geminal capto‐dative substitutents contain a donor and an acceptor group bonded to the same C atom;such substitution stabilizes radicals. Compound 1 is an example; its remarkable Cl,H disproportionation to give the glyoxalic ester derivative 2 probably proceeds via a radical. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：615 / 616

页数：2

共 12 条

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[2]

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HUYS F, 1979, THESIS U LOUVAIN LA

[6] CAPTO-DATIVE SUBSTITUTION EFFECTS .4. INTRA-MOLECULAR CL,H DISPROPORTIONATION OF AN OXAMIDE CHLORIDE - ENTRY TO IMIDAZOLE DERIVATIVES [J].

JANOUSEK, Z ;

HUYS, F ;

RENE, L ;

MASQUELIER, M ;

STELLA, L ;

MERENYI, R ;

VIEHE, HG .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (08) :616-617

[7]

JANOUSEK Z, 1979, ANGEW CHEM, V91, P651

[8]

POMMELET JC, UNPUBLISHED

[9] STABILIZATION OF RADICALS BY CAPTO-DATIVE SUBSTITUTION-C-C ADDITION TO RADICOPHILIC OLEFINS [J].

STELLA, L ;

JANOUSEK, Z ;

MERENYI, R ;

VIEHE, HG .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (09) :691-692

[10]

STELLA L, 1978, ANGEW CHEM, V90, P741

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