ISOTOPE EFFECT ON HYDROGEN-BOND LENGTH

被引：88

作者：

SINGH, TR

WOOD, JL

机构：

[1] Department of Chemistry, Imperial College of Science and Technology, London, S.W.7, Imperial Institute Road

[2] Department of Chemistry, University of Western Ontario, London, Ont.

[3] Department of Chemistry, University of California, Davis, CA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 08期

关键词：

D O I：

10.1063/1.1671587

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using the Stepanov approximation, computer calculations have been made of the effect of deuterium substitution on the length of the hydrogen bond. Expansion on replacement with deuterium is a feature of both symmetric and asymmetric double-minimum potentials, contraction of single-minimum potentials. The origin of the effect and its relation to observations is discussed.

引用

页码：3572 / &

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