FLUORIDOLYSIS OF CYCLOPHOSPHAZENES AND LINEARY POLYPHOSPHAZENES

被引：0

作者：

LOWE, C ^{[1
]}

RIESEL, L ^{[1
]}

机构：

[1] HUMBOLDT UNIV BERLIN,FACHBEREICH CHEM,D-13055 BERLIN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 05期

关键词：

FLUORIDOLYSIS; CYCLOPHOSPHAZENES; POLYPHOSPHAZENES;

D O I：

10.1002/zaac.19956210532

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The fluorination of nongeminal trans P3N3Cl4(NEt(2))(2) and nongeminal trans P3N3Cl3(NEt(2))(3) with the fluorination agent Et(3)N . 0,6HF (B) occurs under retention of configuration yielding P3N3Cl2F2(NEt(2))(2) and P3N3F4(NEt(2))(2) or P3N3F3(NEt(2))(3), respectively. P3N3Cl6 is nearly quantitatively converted into P3N3F6. Poly(dichlorophosphazene) reacts to a poly(difluorophosphazene), (PNF2)(n), distinguished by a moderate solubility in THF.

引用

页码：901 / 903

页数：3

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