SYNTHESIS OF TRIS(BETA-DIKETONATO)INDIUM FROM METALLIC INDIUM AND BIS(BETA-DIKETONATO)COPPER

被引:1
|
作者
WAKESHIMA, I
WATANABE, S
KIJIMA, I
机构
关键词
D O I
10.1246/bcsj.67.2583
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction between metallic indium and bis-(beta-diketonato)copper(II) in non-aqueous solution produced the corresponding indium chelate compounds of the type [In(dik)3], where Hdik denotes CH3COCH2COCH3 (Hacac), CH3COCH2COC6H5 (Hbzac), C6H5COCH2COC6H5 (Hdbzm), or (CH3)3CCOCH2COC(CH3)3 (Hdpm). The [In(acac)3] was formed in high yield by the reactions using o-dichlorobenzene, decaline, or DMSO as solvent. The other indium chelate compounds were synthesized by reactions using DMSO as solvent.
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页码:2583 / 2585
页数:3
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