SYNTHESIS AND CATALYTIC PROPERTIES OF AN ACYCLIC ANALOG OF HYDROXY NORPHOS

被引：33
作者：
BORNER, A
WARD, J
RUTH, W
HOLZ, J
KLESS, A
HELLER, D
KAGAN, HB
机构：
[1] UNIV ROSTOCK,FACHBEREICH CHEM,D-18055 ROSTOCK,GERMANY
[2] UNIV PARIS 11,SYNTH ASYMETR LAB,CNRS,URA 1497,F-91405 ORSAY,FRANCE
来源：
TETRAHEDRON | 1994年 / 50卷 / 35期
关键词：
D O I：
10.1016/S0040-4020(01)89582-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of (S)-1,2-bis(diphenylphosphino)butane-4-ol 1 an acyclic analogue of hydroxy norphos is described, starting from L-ascorbic acid. Problems which arose during the cleavage of OH-protective groups in the presence of phosphino groups are discussed. The hydrogenation properties of the catalyst derived from the new ligand are compared with those obtained with hydroxy norphos.(1)
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收藏
页码：10419 / 10430
页数：12
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