SYNTHESIS AND CATALYTIC PROPERTIES OF AN ACYCLIC ANALOG OF HYDROXY NORPHOS

被引：33

作者：

BORNER, A

WARD, J

RUTH, W

HOLZ, J

KLESS, A

HELLER, D

KAGAN, HB

机构：

[1] UNIV ROSTOCK,FACHBEREICH CHEM,D-18055 ROSTOCK,GERMANY

[2] UNIV PARIS 11,SYNTH ASYMETR LAB,CNRS,URA 1497,F-91405 ORSAY,FRANCE

来源：

TETRAHEDRON | 1994年 / 50卷 / 35期

关键词：

D O I：

10.1016/S0040-4020(01)89582-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of (S)-1,2-bis(diphenylphosphino)butane-4-ol 1 an acyclic analogue of hydroxy norphos is described, starting from L-ascorbic acid. Problems which arose during the cleavage of OH-protective groups in the presence of phosphino groups are discussed. The hydrogenation properties of the catalyst derived from the new ligand are compared with those obtained with hydroxy norphos.(1)

引用

页码：10419 / 10430

页数：12

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