STABILIZATION OF DIBENZO-PARA-QUINODIMETHANE BY (PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM CATION

被引：12

作者：

GLATZHOFER, DT ^{[1
]}

LIANG, YW ^{[1
]}

KHAN, MA ^{[1
]}

FAGAN, PJ ^{[1
]}

机构：

[1] DUPONT CO INC,CENT RES & DEV,WILMINGTON,DE 19880

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 04期

关键词：

D O I：

10.1021/om00050a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [2.2]anthracenophane (1) with [Cp*Ru(CH3CN)3]+CF3SO3- (Cp* = eta-5-pentamethylcyclopentadienyl) results in cleavage of the ethano bridges to form stable complexes (trans-[(Cp*Ru)2(eta-6:eta-6-dibenzo-p-quinodimethane)]2+(CF3SO3-)2 (3) and [(Cp*Ru)(eta-6-dibenzo-p-quinodimethane)]+CF3SO3- (4)) of the highly reactive dibenzo-p-quinodimethane (2). An X-ray structural analysis of 3 shows the dibenzo-p-quinodimethane moiety to be in a boat conformation.

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页码：833 / 834

页数：2

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