SIMPLE ROUTE TO LI-METALATED OR ZN-METALATED ETA-5-CYCLOPENTADIENYLIRON-OLEFIN COMPLEXES

被引：43
作者：
JONAS, K
SCHIEFERSTEIN, L
机构：
[1] Max-Planck-Institut für Kohlenforschung, Mülheim-Ruhr, D-4330
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 07期
关键词：
D O I：
10.1002/anie.197905492
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Some new reactions of ferrocene with lithium and olefins involve only replacement of a C5H5 ligand. The product, e.g.(1). DME and 1. TMEDA, can be metalated with ZnCl2 or CdCl2 and transformed into trinuclear complexes with olefinic ligands bonded to iron, such as2. Reaction of 1 and trityl chloride produces the monomeric radical CpFe(COD)•. (Formula Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany
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页码：549 / 550
页数：2
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