[(C6H5)(4)P](1)(INFINITY)[CU3I4] - THE FIRST COMPOUND WITH A HELICAL CHAIN OF FACE-SHARING TETRAHEDRA AS A STRUCTURAL ELEMENT

被引：41

作者：

HARTL, H

MAHDJOURHASSANABADI, F

机构：

[1] Institut Für Anorganische Und Analytische Chemie Der Freien Universität, Berlin, D-14195

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 18期

关键词：

D O I：

10.1002/anie.199418411

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Face‐sharing tetrahedra arranged in a helix (idealized form shown below) mark the structure of the iodocuprate 1, which was obtained from Ph4PI, I2, and Cu. Five Cu positions were identified at room temperature; at lower temperatures only three (slow cooling) or four (rapid cooling) are occupied. (Formula Presented.) (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1841 / 1842

页数：2

共 18 条

[1] CRYSTAL-STRUCTURE OF BIS(METHYLTRIBUTYLAMMONIUM) PENTA-MU-BROMO-DI-MU-5-BROMO-PENTACUPRATE(I), A COMPOUND CONTAINING A DISCRETE [CU5BR7]2- AGGREGATE [J].

ANDERSSON, S ;

JAGNER, S .

JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH, 1988, 18 (05) :591-600

[2] SYNTHESES AND STRUCTURE ANALYSES OF IODOCUPRATES(I) .9. SYNTHESES AND CRYSTAL-STRUCTURES OF CS3CU2I5 AND RBCU2I3 [J].

BIGALKE, KP ;

HANS, A ;

HARTL, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 563 (08) :96-104

[3]

BOERDIJK AH, 1952, PHILIPS RES REP, V7, P303

[4]

Buckminster-Fuller R., 1982, SYNERGETICS, P520

[5]

FRYDRYCH R, 1989, Z NATURFORSCH B, V45, P679

[6]

HARTL H, 1985, Z NATURFORSCH B, V40, P1032

[7] SYNTHESIS AND STRUCTURAL INVESTIGATION OF IODOCUPRATES(I) .4. [CU5I7]2- - AN ISOPOLYANION WITH CYCLIC FACE-TO-FACE LINKING OF CUI4 TETRAHEDRA [J].

HARTL, H ;

MAHDJOURHASSANABADI, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (05) :378-379

[8] SYNTHESIS AND STRUCTURAL INVESTIGATION OF IODOCUPRATES(I) .7. [(CO(CP)2)(CUI23)]3, [(CO(CP)2)(CUI2)]4, COBALTOCENIUM IODOCUPRATES(I) WITH UNUSUAL ANION STRUCTURES [J].

HARTL, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (09) :927-928

[9]

HARTL H, 1984, Z NATURFORSCH B, V39, P149

[10]

HARTL H, 1981, ANGEW CHEM INT EDIT, V30, P772

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