The Vibrational Spectra and Structures of Perbromyl and Perchloryl Fluorides

被引：30

作者：

Claassen, Howard H. ^{[1
]}

Appelman, Evan H. ^{[1
]}

机构：

[1] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA

来源：

INORGANIC CHEMISTRY | 1970年 / 9卷 / 03期

关键词：

D O I：

10.1021/ic50085a038

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Raman and infrared spectra of BrO3F gas and the Raman spectrum of ClO3F gas are reported. The ClO3F results confirm the tetrahedral C-3v symmetry indicated by earlier work, and the BrO3F results support a similar structure for it. The fundamental frequencies of BrO3F are 875.5, 605.0, and 359.8 cm(-1), for species a(1) and 976.5, 382.0, and 286 cm(-1), for species e.

引用

页码：622 / 624

页数：3

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