MOLECULAR AND CRYSTAL-STRUCTURE OF 2,2',5,5'-TETRAMETHYL-1,1'-DISTIBAFERROCENE - A SHORT SB=SB INTER-RING CONTACT

被引：31

作者：

ASHE, AJ ^{[1
]}

DIEPHOUSE, TR ^{[1
]}

KAMPF, JW ^{[1
]}

ALTAWEEL, SM ^{[1
]}

机构：

[1] MUTAH UNIV,DEPT NAT SCI,AL KARAK,JORDAN

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 06期

关键词：

D O I：

10.1021/om00052a065

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2,2',5,5'-Tetramethyl-1,1'-distibaferrocene (13) was obtained from the reaction of 1-phenyl-2,5-dimethylstibole with lithium followed by FeCl2. Red crystals of 13 form in Pc space group with Z = 2, a = 6.811 (1) angstrom, b = 11.336 (3) angstrom, c = 8.918 (3) angstrom, and beta = 102.80 (2)degrees. The full structure has been determined and shows a ferrocene-like arrangement with a close (3.68 angstrom) inter-ring Sb...Sb contact.

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页码：2068 / 2071

页数：4

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