A SERIES 2ND-1ST-ORDER MECHANISM FOR THE OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS BY CR(VI) REAGENTS

被引：17

作者：

AGARWAL, S ^{[1
]}

TIWARI, HP ^{[1
]}

SHARMA, JP ^{[1
]}

机构：

[1] UNIV ALLAHABAD,DEPT CHEM,ALLAHABAD 211002,UTTAR PRADESH,INDIA

来源：

TETRAHEDRON | 1990年 / 46卷 / 06期

关键词：

D O I：

10.1016/S0040-4020(01)89764-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Based on the experimental data, a definite mechanism for the oxidation of primary and secondary alcohols with PCC and two newly synthesized Cr(VI) reagents has been proposed. The reaction has been shown to be a series reaction rather than a simple one step reaction as reported in the literature. The mechanism proposed has been exemplified by taking 2-pentanol as an example. The kinetic isotope studies have also been performed. © 1990.

引用

页码：1963 / 1974

页数：12

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