SIMPLE METHOD OF HYDROGEN INSERTION IN TRANSITION-METAL OXIDES TO OBTAIN BRONZES

被引：18

作者：

AYYAPPAN, S ^{[1
]}

RAO, CNR ^{[1
]}

机构：

[1] INDIAN INST SCI,MAT RES CTR,BANGALORE 560012,KARNATAKA,INDIA

来源：

MATERIALS RESEARCH BULLETIN | 1995年 / 30卷 / 08期

关键词：

HYDROGEN BRONZES; HXWO3; H0.47MOO3; H0.4V2O5;

D O I：

10.1016/0025-5408(95)00088-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Reaction of WO3, MoO3 and V2O5 with alcohols or glycols is shown to yield hydrogen bronzes of the oxides. Cubic and tetragonal HxWO3, H-0.47 MoO3 as well as H0.4V2O5 have been prepared by this metnod.

引用

页码：947 / 951

页数：5

共 12 条

[1] PHASE RELATIONSHIPS IN SYSTEM HXMOO3 (0 LESS-THAN-OR-EQUAL-TO X LESS-THAN-OR-EQUAL-TO 2.0) [J].

BIRTILL, JJ ;

DICKENS, PG .

MATERIALS RESEARCH BULLETIN, 1978, 13 (04) :311-316

[2]

CHOAIN C, 1963, B SOC CHIM FR, P212

[3] X-RAY AND NEUTRON DIFFRACTION STUDIES OF A TETRAGONAL HYDROGEN BRONZE HXWO3 [J].

DICKENS, PG ;

HURDITCH, RJ .

NATURE, 1967, 215 (5107) :1266-&

[4] HYDROGEN INSERTION COMPOUNDS OF V6O13 AND V2O5 [J].

DICKENS, PG ;

CHIPPINDALE, AM ;

HIBBLE, SJ ;

LANCASTER, P .

MATERIALS RESEARCH BULLETIN, 1984, 19 (03) :319-324

[5]

DICKENS PG, 1992, PROTON CONDUCTORS

[6]

DICKENS PG, 1989, SOLID STATE IONICS, V18, P89

[7]

JAMES GS, 1981, THESIS U OXFORD

[8]

Rao C., 1994, CHEM APPROACHES SYNT

[9]

SCHROEDER FA, 1987, GMELIN HDB ANORGANIS

[10] STUDIES OF HYDROGEN SPILLOVER .1. STUDY OF RATE, EXTENT AND PRODUCTS OF HYDROGEN SPILLOVER FROM PLATINUM TO TRIOXIDES OF TUNGSTEN AND MOLYBDENUM [J].

SERMON, PA ;

BOND, GC .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1976, 72 :730-744

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