REACTION OF AR+ WITH PF5, PF3, AND NF3

被引：17

作者：

MILLER, TM

FRIEDMAN, JF

MILLER, AES

PAULSON, JF

机构：

[1] Phillips Laboratory, Geophysics Directorate, Ionospheric Effects Division (PL/GPID), Hanscom AFB, MA 01731-3010

[2] Orion International Technologies, Albuquerque, NM

[3] Department of Physics and Astronomy, University of Oklahoma, Cambridge

[4] Department of Physics, University of Puerto Rico, Mayagüez

[5] Department of Chemistry and Biochemistry, University of Oklahoma, Cambridge

[6] Department of Chemistry, 6-234B, Massachusetts Institute of Technology, Cambridge

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 24期

关键词：

D O I：

10.1021/j100075a017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rate coefficients have been measured over the temperature range 300-550 K for the reactions of Ar+ with PF5, PF3, and NF3, using a flowing-afterglow apparatus. The rate coefficients were found to be either collisional in magnitude or nearly so, and independent of temperature within experimental uncertainty. These reactions proceed by dissociative charge transfer, releasing F atoms. The ionic products of Ar+ reactions are PF4+ from PF5, PF2+ from PF3, and NF2+ from NF3. He+ was observed to react rapidly with PF5, PF3, and NF3.

引用

页码：6144 / 6147

页数：4

共 58 条

[1]

Adams N. G., 1988, TECHNIQUES STUDY ION, P165

[2] ANOMALOUS TEMPERATURE-DEPENDENCE OF THE COEFFICIENT OF ELECTRON-ATTACHMENT TO HEXAFLUOROBENZENE [J].

ADAMS, NG ;

SMITH, D ;

ALGE, E ;

BURDON, J .

CHEMICAL PHYSICS LETTERS, 1985, 116 (06) :460-464

[3]

[Anonymous], 1963, TABLES EXPT DIPOLE M

[4]

Bartlett N., 1982, INTERCALATION CHEM, V2, P19

[5] POTENTIAL FUNCTION FOR AXIAL-EQUATORIAL FLUORINE ATOM EXCHANGE IN PF-5, ASF-5, AND VF-5 [J].

BERNSTEIN, LS ;

ABRAMOWITZ, S ;

LEVIN, IW .

JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (08) :3228-3236

[6] CORRELATION OF RATES OF INTRAMOLECULAR TUNNELING PROCESSES, WITH APPLICATION TO SOME GROUP-V COMPOUNDS [J].

BERRY, RS .

JOURNAL OF CHEMICAL PHYSICS, 1960, 32 (03) :933-938

[7] FLOWING AFTERGLOW STUDIES OF REACTIONS OF RARE-GAS MOLECULAR IONS HE2+, NE2+, AND AR2+WITH MOLEDULES AND RARE-GAS ATOMS [J].

BOHME, DK ;

ADAMS, NG ;

MOSESMAN, M ;

DUNKIN, DB ;

FERGUSON, EE .

JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (10) :5094-+

[8] ABINITIO CALCULATION OF HARMONIC FORCE-FIELDS AND VIBRATIONAL-SPECTRA FOR THE FLUOROPHOSPHORANES PH-N-F5-N (N = 0-5) [J].

BREIDUNG, J ;

THIEL, W ;

KOMORNICKI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (20) :5603-5611

[9] MECHANISM OF THERMAL-ENERGY CHARGE-TRANSFER REACTIONS - HE+.,NE+.,AR+.,KR+.,XE+.,N2+.,CO+.,CO2+., AND N2O+. REACTING WITH CH3F, CH2F2, CHF3 AND CF4 [J].

CHAU, M ;

BOWERS, MT .

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1977, 24 (02) :191-197

[10] ANION-EXCHANGE IN NF4+ SALTS USING GRAPHITE SALTS AS AN OXIDIZER-RESISTANT AND ACID-RESISTANT ANION-EXCHANGE MEDIUM [J].

CHRISTE, KO ;

WILSON, RD .

INORGANIC CHEMISTRY, 1989, 28 (22) :4175-4177

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