ON THE CRYSTAL-STRUCTURE OF BA3IN2ZN5O11 - AN OXOINDATE ZINCATE WITH ZN10O20 AND IN4O16 MACROPOLYHEDRA WITH ZN-2+ IN TETRAHEDRAL COORDINATION BY O-2-

被引：20

作者：

SCHEIKOWSKI, M ^{[1
]}

MULLERBUSCHBAUM, H ^{[1
]}

机构：

[1] UNIV KIEL,INST ANORGAN CHEM,OLSHAUSENSTR 40-60,W-2300 KIEL 1,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 03期

关键词：

BARIUM; INDIUM; ZINC; OXIDE; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19936190322

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ba3In2Zn5O11 was prepared for the first time by a flux technique and investigated by single crystal X-ray work. It crystallizes with cubic symmetry, space group T(d)2-F43mBAR, a = 13.3588 angstrom, Z = 8. Zn2+ show tetrahedral coordination by O2-, forming Zn10O20 macropolyhedra. In addition the Zn/O part of the crystal structure is made up of Zn10O20 parts. Edge connection of four InO6 octahedra results in In4O16 groups. The crystal structure will be shown and discussed.

引用

页码：559 / 562

页数：4

共 32 条

[1]

ALATYRTSEVA TA, 1979, ZH NEORG KHIM+, V24, P1256

[2] K2ZN3O4 AND RB2ZN3O4 OXOZINCATES WITH FRAMEWORK STRUCTURE [J].

BAIER, R ;

HOPPE, R .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1987, 551 (08) :163-172

[3] CRYSTAL CHEMISTRY OF INDATES - CALCIUM, CADMIUM, STRONTIUM AND BARIUM INDATES [J].

CRUICKSHANK, FR ;

TAYLOR, DM ;

GLASSER, FP .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1964, 26 (06) :937-941

[4]

ENSSLIN F, 1947, Z NATURFORSCH B, V2, P5

[5] SYSTEMS LI2O-COO AND LI2O-ZNO [J].

JANSEN, M ;

KASTNER, P ;

HOPPE, R .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1975, 414 (01) :69-75

[6]

JOHNSON CK, 1965, ORNL3794 REP

[7] SYNTHESIS OF BA4IN6O13 [J].

KANAMARU, F ;

KOIZUMI, M .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1973, 56 (07) :399-400

[8] COMPOUNDS IN SYSTEM BAO-IN203 [J].

KWESTROO, W ;

VANGERVEN, HCA ;

LANGEREIS, C .

MATERIALS RESEARCH BULLETIN, 1977, 12 (02) :157-160

[9] 2 NEW ALKALINE-EARTH-OXOINDATES - BACA2IN6O12 AND BASR2IN6O12 [J].

LALLA, A ;

MULLERBUSCHBAUM, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 563 (08) :11-15

[10] THE MEO - M2O3 SYSTEM .11. CRYSTAL-STRUCTURE OF BAIN2O4 [J].

LALLA, A ;

MULLERBUSCHBAUM, H .

JOURNAL OF THE LESS-COMMON METALS, 1989, 154 (02) :233-241

← 1 2 3 4 →