PHOSPHINE-LIGANDS .2. BIDENTATE PHOSPHINES OF HETEROARENES - 4,6-BIS(DIPHENYLPHOSPHINO)DIBENZOFURAN AND 4,6-BIS(DIPHENYLPHOSPHINO)DIBENZOTHIOPHENE

被引：55
|
作者：
HAENEL, MW
JAKUBIK, D
ROTHENBERGER, E
SCHROTH, G
机构：
[1] Max-Planck-Institut für Kohlenforschung, Mülheim/Ruhr, W-4330
来源：
CHEMISCHE BERICHTE | 1991年 / 124卷 / 08期
关键词：
PHOSPHINE LIGANDS; DIBENZOFURAN; DIBENZOTHIOPHENE; LITHIUM COMPOUNDS; MULTIPLE LITHIATION;
D O I：
10.1002/cber.19911240806
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Twofold lithiation of dibenzofuran (6) and dibenzothiophene (12) with n-butyllithium/N,N,N',N'-tetramethylethylenediamine (TMEDA) in n-hexane or n-pentane followed by the reaction with chlorodiphenylphosphine yielded the title compounds 4 and 5, respectively. The monophosphines 4-(diphenylphosphino)dibenzofuran (11) and 4-(diphenylphosphino)dibenzothiophene (15) were obtained analogously via the monolithium compounds 9 and 14 of the heteroarenes. In the case of dibenzofuran (6), it was shown that mono- and dilithiation is controlled by temperature.
引用
收藏
页码：1705 / 1710
页数：6
相关论文
共 50 条
  • [31] Methyl 4,6-bis(4-fluorophenyl)-2-oxocyclohex-3-ene-1-carboxylate
    Fun, Hoong-Kun
    Hemamalini, Madhukar
    Samshuddin, S.
    Narayana, B.
    Yathirajan, H. S.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O864 - U2604
  • [32] Bis(4,4′-bipyridyl)bis{2-[4,6-bis(carboxymethylsulfanyl)-1,3,5-triazin-2-ylsulfanyl]acetato}zinc(II)
    Wang, Suna
    Yang, Yan
    Li, Dacheng
    Dou, Jianmin
    Wang, Daqi
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M370 - U364
  • [33] Synthesis and characterization of degradable polyimides derived from 4,6-bis(4-aminophenoxy) pyrimidine
    Cui, Changsheng
    HIGH PERFORMANCE POLYMERS, 2015, 27 (03) : 362 - 370
  • [34] SYNTHESIS OF 2-ARYLHYDROXY-4,6-BIS(4-CARBOXYPHENYL)-SYM-TRIAZINES AND THEIR CHLOROANHYDRIDES
    AVANESYAN, ES
    ZAPLISHNYI, VN
    POGOSYAN, GM
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1983, (08): : 1125 - 1129
  • [35] Crystal structure of 2-butylsulfanyl-4,6-bis[(E)-4-(dimethylamino)styryl]-pyrimidine
    Song, Jingbao
    Zhou, Qiang
    Wang, Aijian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O978 - U861
  • [36] STRUCTURE OF 4,6-BIS(TRIFLUOROMETHYL)-2,2-BIS[2,4,6-TRIS(TRIFLUOROMETHYL)PHENYLTHIO]-1-THIABENZOCYCLOBUTENE
    POHL, E
    HERBSTIRMER, R
    SHELDRICK, GM
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 1026 - 1028
  • [37] RUPTURE AND REALIGNMENT OF THE BRIDGING PHOSPHINE FRAMEWORK IN THE REACTIONS OF POLYNUCLEAR RHODIUM COMPLEXES OF 2,6-BIS(DIPHENYLPHOSPHINO)PYRIDINE
    WOOD, FE
    HVOSLEF, J
    BALCH, AL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (23) : 6986 - 6987
  • [38] Synthesis, structural analysis and solvatochromic behaviour of 4,6-bis (4-butoxyphenyl)-2-methoxynicotinonitrile mesogen
    Ahipa, T. N.
    Kumar, Vijith
    Adhikari, Airody V.
    LIQUID CRYSTALS, 2013, 40 (01) : 31 - 38
  • [39] 4,6-DIACETYLRESORCINOL IN HETEROCYCLIC SYNTHESIS PART II: SYNTHESIS OF SOME NOVEL 4,6-BIS(AZOLYL/AZINYL/AZEPINYL)RESORCINOLS
    Assiri, Mohammed A.
    Ali, Tarik E.
    Ibrahim, Magdy A.
    El-Amin, E. M.
    Yahia, I. S.
    HETEROCYCLES, 2019, 98 (01) : 114 - 125
  • [40] REACTIONS OF 4,6-BIS(ACETYL)RESORCINOL WITH ALKOXYCARBONYLALKYLIDENE(TRIPHENYL)PHOSPHORANES - PREPARATION OF COUMARIN DERIVATIVES
    NICOLAIDES, DN
    FYLAKTAKIDOU, KC
    BEZERGIANNIDOUBALOUKTSI, C
    LITINAS, KE
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 1994, 31 (01) : 173 - 176
12345