1ST EXAMPLE OF DIRECT CARBON-DIOXIDE INCORPORATION INTO 1,3-DIYNES - A HIGHLY REGIOSELECTIVE AND STEREOSELECTIVE NICKEL-CATALYZED ELECTROCHEMICAL REACTION

被引：31

作者：

DERIEN, S

CLINET, JC

DUNACH, E

PERICHON, J

机构：

[1] CNRS, UMR 28, ELECTROCHIM CATALYSE & SYNTH ORGAN LAB, 2 RUE HENRI DUNANT, F-94320 THIAIS, FRANCE

[2] UNIV PARIS 11, CHIM ELEMENTS TRANSIT LAB, CNRS, URA 255, F-91405 ORSAY, FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 08期

关键词：

D O I：

10.1039/c39910000549

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrosynthesis of 2-vinylidene-3-yne carboxylic acids from carbon dioxide and substituted 1,3-diynes is catalysed by a nickel-triamine complex and results in a regio- and stereo-selective addition to one triple bond.

引用

页码：549 / 550

页数：2

共 11 条

[1]

Brandsma L., 1988, PREPARATIVE ACETYLEN

[2] REACTIONS OF CARBON-DIOXIDE WITH CARBON CARBON BOND FORMATION CATALYZED BY TRANSITION-METAL COMPLEXES [J].

BRAUNSTEIN, P ;

MATT, D ;

NOBEL, D .

CHEMICAL REVIEWS, 1988, 88 (05) :747-764

[3]

CHAUSSARD J, 1990, SYNTHESIS-STUTTGART, P369

[4] ELECTROGENERATED NICKEL(0) CATALYZED CARBON-DIOXIDE INCORPORATION INTO ALPHA,OMEGA-DIYNES [J].

DERIEN, S ;

DUNACH, E ;

PERICHON, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 385 (03) :C43-C46

[5]

DUNACH E, 1990, SYNLETT, P143

[6] ELECTROCHEMICAL CARBOXYLATION OF TERMINAL ALKYNES CATALYZED BY NICKEL-COMPLEXES - UNUSUAL REGIOSELECTIVITY [J].

DUNACH, E ;

PERICHON, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 352 (1-2) :239-246

[7] NICKEL(0)-INDUCED C-C COUPLING BETWEEN CARBON-DIOXIDE AND ALKYNES AS WELL AS ALKENES [J].

HOBERG, H ;

SCHAEFER, D ;

BURKHART, G ;

KRUGER, C ;

ROMAO, MJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 266 (02) :203-224

[8] REACTION OF DIALKYL-SUBSTITUTED ALKYNES WITH CARBON-DIOXIDE CATALYZED BY NICKEL(0) COMPLEXES - INCORPORATION OF CARBON-DIOXIDE IN ALKYNE DIMERS AND NOVEL CYCLOTRIMERIZATION OF THE ALKYNES [J].

INOUE, Y ;

ITOH, Y ;

KAZAMA, H ;

HASHIMOTO, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (11) :3329-3333

[9] NICKEL(0)-CATALYZED CYCLO-ADDITION OF DIYNES AND CARBON-DIOXIDE TO BICYCLIC ALPHA-PYRONES [J].

TSUDA, T ;

MORIKAWA, S ;

SUMIYA, R ;

SAEGUSA, T .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (14) :3140-3145

[10] HOMOGENEOUS-CATALYTIC REACTIONS OF CARBON-DIOXIDE WITH UNSATURATED SUBSTRATES, REVERSIBLE CO2-CARRIERS AND TRANSCARBOXYLATION REACTIONS [J].

WALTHER, D .

COORDINATION CHEMISTRY REVIEWS, 1987, 79 (1-2) :135-174

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