MECHANISM OF ELIMINATION OF AN H2O MOLECULE IN DESMETHYLENCECALIN UNDER ELECTRON-IMPACT

被引：0

作者：

NAKAYAMA, M

EGUCHI, S

HAYASHI, S

TSUKAYAMA, M

NAKATA, H

机构：

[1] TOKUSHIMA UNIV,FAC ENGN,DEPT APPL CHEM,TOKUSHIMA 770,JAPAN

[2] AICHI KYOIKU UNIV,DEPT CHEM,KARIYA,AICHI 448,JAPAN

来源：

ORGANIC MASS SPECTROMETRY | 1979年 / 14卷 / 12期

关键词：

D O I：

10.1002/oms.1210141209

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The mass spectrum of desmethylencecalin has been measured and a fragmentation mechanism for the loss of a water molecule from the [MCH3]+ ion is proposed on the basis of isotope labelling and metastable peak observations. The eliminated water has been shown to involve the carbonyl oxygen and hydrogen atoms of the hydroxyl and acetyl groups. Copyright © 1979 John Wiley & Sons, Ltd.

引用

页码：672 / 675

页数：4

共 17 条

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