PHENOLIC CONSTITUENTS OF GLYCYRRHIZA SPECIES .14. VARIATIONS IN THE CHEMICAL-SHIFT OF THE 5-HYDROXYL PROTON OF ISOFLAVONES - 2 ISOFLAVONES FROM LICORICE

被引：16

作者：

FUKAI, T ^{[1
]}

NISHIZAWA, J ^{[1
]}

NOMURA, T ^{[1
]}

机构：

[1] TOHO UNIV,FAC PHARMACEUT SCI,FUNABASHI,CHIBA 274,JAPAN

来源：

PHYTOCHEMISTRY | 1994年 / 36卷 / 01期

关键词：

GLYCYRRHIZA URALENSIS; LEGUMINOSAE; LICORICE; KANZOH; PRENYLATED ISOFLAVONE; KANZONOLS K AND L; H-1; NMR;

D O I：

10.1016/S0031-9422(00)97042-0

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

H-1 NMR examination of 6- or 8-prenylated isoflavones has shown that the location of the prenyl side chain on the A ring can be deduced from the chemical shift of the 5-hydroxyl proton. The effects of B ring substituents and methylation of the 7-hydroxyl group on the 5-hydroxyl signal, and the application of this technique to the identification of two prenylated isoflavones, kanzonols K and L, isolated from Glycyrrhiza uralensis are also discussed.

引用

页码：225 / 228

页数：4

共 16 条

[1]

FUKAI T, 1993, HETEROCYCLES, V36, P2565

[2]

FUKAI T, 1991, HETEROCYCLES, V32, P499

[3]

FUKAI T, 1993, HETEROCYCLES, V36, P329

[4]

FUKAI T, 1990, HETEROCYCLES, V31, P373

[5]

FUKAI T, 1992, HETEROCYCLES, V34, P1213

[6]

FUKAI T, 1990, HETEROCYCLES, V31, P1861

[7]

FUKAI T, 1991, 33RD S CHEM NAT PROD, P549

[8]

FUKAI T, 1993, 9TH S DEV APPL NAT O, P49

[9] FLAVONOIDS AND A BENZOFURAN IN ROOTS OF EUCHRESTA-TUBULOSA [J].

MATSUURA, N ;

IINUMA, M ;

TANAKA, T ;

MIZUNO, M .

PHYTOCHEMISTRY, 1993, 33 (03) :701-705

[10] ISOFLAVONES FROM ROOTS OF EUCHRESTA-JAPONICA [J].

MIZUNO, M ;

MATSUURA, N ;

IINUMA, M ;

TANAKA, T .

PHYTOCHEMISTRY, 1992, 31 (02) :675-678

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