Infrared spectra of matrix isolated ammonia at liquid helium temperature, behavior during irradiation with a CO2 laser beam

被引：22

作者：

Abouaf-Marguin, L. ^{[1
]}

Dubost, H. ^{[1
]}

Legay, F. ^{[1
]}

机构：

[1] Fac Sci, Labs Rech Phys, Paris, France

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 7卷 / 01期

关键词：

D O I：

10.1016/0009-2614(70)80249-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Infrared spectra of NH3 trapped in an argon matrix are studied in the nu(2) vibrational region. Under irradiation with a CO2 laser at 975 cm(-1), the spectrum is reversibly changed and, in particular, two nets lines appear. This phenomenon has probably a thermal origin; however a weak resonance effect is possible. It can only be understood with the assumption of molecular rotation of NH3 in the matrix. It confirms the proposed assignment of the rotational lines.

引用

页码：61 / 64

页数：4

共 16 条

[1]

BAGDANSKIS NI, 1965, OPT SPECTROSC-USSR, V19, P128

[2] INFRARED-INFRARED DOUBLE RESONANCE [J].