TERNARY COMPOUNDS REMSB(2), RE=LA, CE, PR, ND, SM, GD, M=MN, ZN, CD - COMPOUND FORMATION, CRYSTAL-STRUCTURE AND MAGNETISM

被引：41
|
作者：
SOLOGUB, O
HIEBL, K
ROGL, P
BODAK, O
机构：
[1] UNIV VIENNA,INST PHYS CHEM,A-1090 VIENNA,AUSTRIA
[2] LVOV IVAN FRANKO STATE UNIV,INST INORGAN CHEM,LVOV 290005,UKRAINE
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 1995年 / 227卷 / 01期
关键词：
CRYSTAL STRUCTURE; COMPOUND FORMATION; MAGNETISM; X-RAY POWDER DIFFRACTION;
D O I：
10.1016/0925-8388(95)01619-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ternary compounds REMnSb(2) (RE=La, Ce, Pr, Nd, Sm), REZnSb(2) (RE=La, Ce, Pr, Nd, Sm, Gd) and RE=dSb(2) (RE = La, Ce, Pr, Nd, Sm) were synthesized. From room temperature X-ray powder diffractometry all compounds were found to crystallize with the ZrCuSi2-type structure. The magnetic behavior of REMnSb, compounds is characterized by the onset of ferromagnetism of the Mn sublattice in the temperature range between 100 and 520 K. Ordering of the rare-earth sublattice below 50 K is indicated for samples containing Ce, Pr and Nd. CeZnSb2 remains paramagnetic in the temperature range investigated (4.2-550 K).
引用
收藏
页码：40 / 43
页数：4
相关论文
共 50 条
  • [31] CRYSTAL-STRUCTURE OF RGANI COMPOUNDS (R=CE,PR,ND,SM,GD,TB,DY,HO,ER,TM,YB,LU,Y)
    YARMOLYUK, YP
    GRYN, YN
    GLADYSHEVSKY, EI
    DOPOVIDI AKADEMII NAUK UKRAINSKOI RSR SERIYA A-FIZIKO-MATEMATICHNI TA TECHNICHNI NAUKI, 1979, (09): : 771 - 775
  • [32] Crystal growth, microhardness and oxidation behavior of RMn2Si2 compounds (R = La, Ce, Pr, Nd, Sm, Gd)
    Okada, S
    Iizumi, K
    Mori, T
    Shishido, T
    Kudou, K
    Tanaka, T
    Rogl, P
    Lundström, T
    JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 383 (1-2) : 254 - 258
  • [33] THE CRYSTAL-STRUCTURE OF RGACO (R=PR, ND, SM, GD, TB, DY, HO, ER, Y) COMPOUNDS
    SICHEVICH, OM
    GLADYSHEVSKY, RE
    GRYN, YN
    YARMOLYUK, YP
    DOPOVIDI AKADEMII NAUK UKRAINSKOI RSR SERIYA B-GEOLOGICHNI KHIMICHNI TA BIOLOGICHNI NAUKI, 1982, (11): : 57 - 59
  • [34] NEW TERNARY PHOSPHIDES R3NI7P5 (R=LA, PR, ND, SM, GD, TB) AND THEIR CRYSTAL-STRUCTURE
    CHIKHRIY, SI
    ORISHIN, SV
    KUZMA, YB
    GLOVYAK, T
    KRISTALLOGRAFIYA, 1989, 34 (05): : 1131 - 1135
  • [35] TERNARY INTERMETALLIC COMPOUNDS WITH ALB2-TYPE STRUCTURE IN LA(CE, PR, ND, SM, EU)-NI(CU)-IN SYSTEMS
    BARANYAK, VM
    DMYTRAKH, OV
    KALYCHAK, YM
    ZAVALII, PY
    INORGANIC MATERIALS, 1988, 24 (05) : 739 - 740
  • [36] A NEW FAMILY OF RARE-EARTH COMPOUNDS, THE TERNARY SILICIDES RE2RHSI3 (RE = Y, LA, CE, ND, SM, GD, TB, DY, HO, ER) - CRYSTAL-STRUCTURE ELECTRICAL AND MAGNETIC-PROPERTIES
    CHEVALIER, B
    LEJAY, P
    ETOURNEAU, J
    HAGENMULLER, P
    SOLID STATE COMMUNICATIONS, 1984, 49 (08) : 753 - 760
  • [37] Ternary antimonides LnM(1-x)Sb(2) with Ln=La-Nd,Sm,Gd,Tb and M=Mn,Co,Au,Zn,Cd
    Wollesen, P
    Jeitschko, W
    Brylak, M
    Dietrich, L
    JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 245 : L5 - L8
  • [38] REBA2CU3O7-DELTA (RE = PR, ND, SM, GD) - CRYSTAL-GROWTH, STRUCTURE AND MAGNETISM
    MORAN, E
    AMADOR, U
    BARAHONA, M
    SAEZ, R
    ALARIO, MA
    VEGAS, A
    SOLID STATE IONICS, 1988, 26 (02) : 167 - 167
  • [39] New compounds with Nd11Pd4In9 structure type in the systems RE-Pd-In (RE = La, Ce, Pr, Nd, Sm, Gd, Tb, Dy)
    Sojka, L.
    Demchyna, M.
    Belan, B.
    Manyako, M.
    Kalychak, Ya
    INTERMETALLICS, 2014, 49 : 14 - 17
  • [40] MAGNETIC-SUSCEPTIBILITY AND CRYSTAL-STRUCTURE OF RNI1-XSN2-Y (R=LA, CE, PR, ND, SM)
    SKOLOZDRA, RV
    SADYKOV, SA
    KOMAROVSKAYA, LP
    KUVANDIKOV, OK
    FIZIKA METALLOV I METALLOVEDENIE, 1988, 65 (03): : 527 - 531
12345